The recent surge
in the usage of electronics has led to a new kind
of problem; electromagnetic interference which necessitates finding
alternate materials that offer ease of processing, design flexibility,
light weight, and ease of embedding and integrating with the existing
systems in place as shields to protect the precise electronic circuitry.
Herein, lightweight polycarbonate (PC)-based nanocomposites using
doped graphene derivatives and multiwalled carbon nanotubes (MWCNT)
has been explored for effective shielding of EM radiation in X- and
Ku-band. To get a mechanistic insight as to how the dopant in graphene
derivatives influences the EM shielding properties, two dopants have
been explored here: ferrimagnetic (ferrite, Fe3O4) and the other one as paramagnetic (gadolinium oxide, Gd2O3). The doped graphene derivatives when composited with
PC and MWCNTs resulted in materials that can shield the incoming EM
radiation through magnetic and dielectric losses. This strategy of
doping improves the state of dispersion of these dopants in the nanocomposites,
besides enhancing the shielding effectiveness. The PC-based nanocomposites
illustrated a total shielding effectiveness (SET) of −28
and −33 dB at 18 GHz for a given concentration of Gd2O3 and Fe3O4 hybrid, respectively.
A closer look into the mechanism of shielding reveals that irrespective
of the dopant, various losses (magnetic and dielectric) decide the
shielding effectiveness in polymeric nanocomposites facilitated by
multiple internal reflections. Taken together, this study brings in
new insight as to how the losses contribute toward effective shielding
rather than the choice of the dopant and will help guide researchers
working in this area from both industrial as well as academic perspective.