Electrolytic Reactions

Fuchigami, Toshio

doi:10.1002/0471762512.ch8

Cited by 4 publications

(4 citation statements)

References 26 publications

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“…Selective anodic fluorination was successfully carried out when RTILs were used as solvent/electrolytes . The selective fluorination of organics is not straightforward due to the high reactivity of most electrophilic fluorinating agents.…”

Section: Organic Electrosynthesismentioning

confidence: 99%

Electrochemical Reactivity in Room-Temperature Ionic Liquids

2008

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Section: Organic Electrosynthesismentioning

confidence: 99%

Electrochemical Reactivity in Room-Temperature Ionic Liquids

2008

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“…As a result, there are ongoing debates on the general structure of the electric double layer in ionic liquids (multilayer vs monolayer, ,− long-range vs short-range, − etc.) as well as on the role of impurities and interfacial dynamics in ionic liquids at charged interfaces. ,− General discussion of these topics is given in ref . In our opinion, the apparent controversy of the subject is due to the following reasons: (i) There are a large number of various ionic liquids with different chemical natures of their ions and, consequently, different physical–chemical properties.…”

Section: Introductionmentioning

confidence: 99%

Screening of Ion–Graphene Electrode Interactions by Ionic Liquids: The Effects of Liquid Structure

2014

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We have investigated the screening of solute ion−electrode interactions in two ionic liquids (1-butyl 3-methylimidazolium tetrafluoroborate [BMIm][BF 4 ] and 1,3dimethylimidazolium chloride [MMIm]Cl) by constructing free energy profiles for dissolved charged probes as a function of distance from a charged surface (graphene). The free energy profiles for three types of mutual interactions (surface and solute with opposite charges, solute and uncharged surface, and surface and solute with the same charges) differ from each other, but are remarkably similar in the two ionic liquids. They all show oscillations rather than the monotonic behavior predicted by Debye-type screening models. In both ionic liquids, there are high barriers impeding the motion of charged probes to the oppositely charged surface. We examined the local liquid structure around the probes and found that the free energy minima correspond to positions in which the solvation layers induced by the surface charge and the solvation shells around the probes enhance each other while barriers occur where they perturb each other.

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“…However, since several years, also room temperature ionic liquids (RTILs) are increasingly being applied for electrochemical and, in particular electrosynthetic, purposes [11][12][13][14]. RTILs are ionic compounds with a melting point below room temperature, and have several interesting properties in the context of the work to be described here.…”

Section: Introductionmentioning

confidence: 99%