1999
DOI: 10.1016/s0378-7753(99)00188-3
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Electrolytes for advanced batteries

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Cited by 98 publications
(73 citation statements)
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“…The time dependence was set to be proportional to the square root of time as reported by several researchers. [86][87][88][89][90][91] The cycle number dependence can come from the SEI repair at the surface of the Si-alloy particles due to the volume changes upon lithiation and delithiation. In these fits, the possibility of lithium plating was ignored since no plating was observed in cells cycled at C/2.…”
Section: Impedance Of Individual Electrodes Of Lco/si-alloy:graphite mentioning
confidence: 99%
“…The time dependence was set to be proportional to the square root of time as reported by several researchers. [86][87][88][89][90][91] The cycle number dependence can come from the SEI repair at the surface of the Si-alloy particles due to the volume changes upon lithiation and delithiation. In these fits, the possibility of lithium plating was ignored since no plating was observed in cells cycled at C/2.…”
Section: Impedance Of Individual Electrodes Of Lco/si-alloy:graphite mentioning
confidence: 99%
“…(4-7). Many researchers studying the failure of Li-ion batteries have identified this capacity loss vs t 1/2 (or equivalent) relationship and have demonstrated that their models fit experimental data very well [16,85,92,95,122].…”
Section: The Growth Rate Of Sei Filmmentioning
confidence: 99%
“… pq (4)(5)(6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16)(17)(18) where is carrier hole mobility, and q is electron charge.…”
Section:  mentioning
confidence: 99%
“…Yoshida et al 5 first reported the formation of DEDOHC (referred to as a transesterification byproduct) in LIBs with 1 M LiPF 6 /EC+DEC (1:1 v/v) electrolyte. Other groups have detected DEDOHC formation by gas chromatography-mass spectroscopy (GC-MS), [6][7][8] and storage tests imply that this product is catalyzed by lithium alkoxide. 8,9 Poly-EC has also been identified to be a product of EC electrolyte degradation, initiated by a Lewis acid such as PF 5 9-11 .…”
Section: Introductionmentioning
confidence: 99%