“…3 The implication is that in general neither electrodes nor embedding dielectric material play an important part in electroluminescence, with the single exception of the very thin films considered in this paper. Neither this observation nor the other experimental results serve to differentiate among the several possible excitation mechanisms of electroluminescence 10, [16][17][18][19][20][21] ; however, other evidence published elsewhere suggests minority carrier injection as most likely. 22 Whatever its nature, the excitation step must depend upon current flow which in turn depends on applied voltage or electric field.…”
Very thin sulfide films emit light only on alternate half-cycles of the voltage sine wave, whereas the emission of thicker films and phosphor powders is quite symmetrical with polarity. This asymmetry of emission, together with clipping or dc bias of the applied voltage, is used to confirm unambiguously that the excitation and recombination steps in electroluminescence are separable and occur sequentially and under different field configurations, and that the recombination is field-driven.
“…3 The implication is that in general neither electrodes nor embedding dielectric material play an important part in electroluminescence, with the single exception of the very thin films considered in this paper. Neither this observation nor the other experimental results serve to differentiate among the several possible excitation mechanisms of electroluminescence 10, [16][17][18][19][20][21] ; however, other evidence published elsewhere suggests minority carrier injection as most likely. 22 Whatever its nature, the excitation step must depend upon current flow which in turn depends on applied voltage or electric field.…”
Very thin sulfide films emit light only on alternate half-cycles of the voltage sine wave, whereas the emission of thicker films and phosphor powders is quite symmetrical with polarity. This asymmetry of emission, together with clipping or dc bias of the applied voltage, is used to confirm unambiguously that the excitation and recombination steps in electroluminescence are separable and occur sequentially and under different field configurations, and that the recombination is field-driven.
“…The phenomenon was discovered in 1936 by G. Destriau under the observations that when a ZnS (later found to be slightly doped with Cu) powder was suspended in an insulator and an intense alternating electric field was applied with capacitor like electrodes, visible light was emitted. This has led to a surge in research activities of EL properties of ZnS, which were mostly undertaken on single-crystals and powder samples [308][309][310][311][312]. The light output of thin-film electroluminescent displays has been very reliable, with little loss after tens of thousands of hours of operation.…”
“…Although several other papers (2)(3)(4)(5) have been published on the electroluminescence of zinc sulfide and zinc sulfoselenides, there has been no description in them of the method of preparation of the phosphors. Infrared stimulable phosphors using a combination of copper and lead as activators were described by Fonda (6) originally and there has 1 Manuscript received May 1, 1953.…”
The preparation of blue, green, and yellow electroluminescent zinc sulfide phosphors is described, The blue and green phosphors contain copper and lead, with the color being determined by the copper and chloride concentration. The yellow phosphors are tripleactivated, containing copper, lead, and manganese.
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