Electric-field-induced instabilities of trilayer of immiscible
thin films confined between both planar and patterned electrodes have
been explored by the linear stability analysis (LSA) and the long-wave
nonlinear simulations. The twin liquid–liquid interfaces of
a trilayer can undergo either in-phase bending or antiphase squeezing
or mixed modes of evolution. The linear and nonlinear analyses together
uncover the conditions under which these modes evolve and subsequently
form an array of interesting, complex patterns. The study confirms
that when the middle layer is of the highest or lowest dielectric
permittivity than the other layers the interfaces undergo a squeezing
mode of deformation. In other cases, the interfaces evolve in the
bending mode, except for the situations where the linear growth coefficient
versus wavenumber curves in the LSA show a bimodal behavior and the
interfaces evolve in a mixed mode. The LSA also highlights the importance
of the ratios of the thermodynamic parameters such as thicknesses,
dielectric permittivities, and interfacial tensions of the films in
altering the length and time scales. Importantly, variation in the
kinetic parameters such as the ratio of the viscosities of the films
can also alter the modes of evolution, relative amplitudes of deformation,
and morphologies at the interfaces. Nonlinear simulations under spatially
varying electric fields uncover several intriguing self-organized
periodic microstructures such as composite core–shell columns,
pin-cushion-like structures, membranes with ordered pores, and arrays
of open/closed embedded/encapsulated microchannels and microdroplets.
Examples of miniaturization of patterns employing patterned electrodes
with periodicity less than the spinodal length scales are also shown.