1996
DOI: 10.1016/0376-7388(95)00217-0
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Electrodialysis in a non-aqueous medium: production of sodium methoxide

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Cited by 46 publications
(24 citation statements)
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“…First, the OH − ions formed at the cathode by water splitting (Figure 1) reacted with the methanol molecules to form reactive methoxide ions (CH3O − ), with sodium ions (Na + ) as counterions (Sridhar, 1996). Then, the methoxide ions attacked the TG molecules to form esters in a process similar to the reaction (1) (Guan and Kusakabe, 2009).…”
Section: Conversion Of Canola Oil In Methanolic and Ethanolic Reactiomentioning
confidence: 99%
See 1 more Smart Citation
“…First, the OH − ions formed at the cathode by water splitting (Figure 1) reacted with the methanol molecules to form reactive methoxide ions (CH3O − ), with sodium ions (Na + ) as counterions (Sridhar, 1996). Then, the methoxide ions attacked the TG molecules to form esters in a process similar to the reaction (1) (Guan and Kusakabe, 2009).…”
Section: Conversion Of Canola Oil In Methanolic and Ethanolic Reactiomentioning
confidence: 99%
“…The transesterification reaction of canola oil, for instance, occurs in the methanol phase where sodium methoxides, the reactive species, are formed by reaction of the methanol molecules with the sodium hydroxide catalyst (Sridhar, 1996). However, during the methoxide formation process, water molecules are formed and parasitic saponification reactions may occur, reducing the yield and quality of the final product (Mardhiah et al, 2017).…”
mentioning
confidence: 99%
“…Bazinet et al [9] developed an electro-acidification technology using BPM for the food industry. Sidhar [10] successfully synthesized acetoacetic ester using BPM with methanol splitting, which initiates novel and green paths for organic synthesis. Our laboratory has prepared thioglycolic acid [11] and FeO 4 2- [12], 2,2-dimethyl-3-hydroxyl propanoic acid using BPM as a separator [13].…”
Section: Introductionmentioning
confidence: 99%
“…However, the bipolar membrane can also realize alcohol splitting; i.e., alcohol is split into alkoxide anions and H + . Sridhar first reported methanol splitting in bipolar membranes [7] and successfully applied it to the production of acetoacetic ester [8].…”
Section: Introductionmentioning
confidence: 99%