2016
DOI: 10.1016/j.jpowsour.2016.06.091
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Electrodes from carbon nanotubes/NiO nanocomposites synthesized in modified Watts bath for supercapacitors

Abstract: h i g h l i g h t sNiO with diameter <4 nm was deposited on multiwalled carbon nanotubes. Pseudocapacitance per mass of NiO of the nanocomposite electrode was very high. Modified Watts bath was effective for the size reducing of Ni species. a b s t r a c t A modified Watts bath coupled with pulsed current electroplating is used to uniformly deposit ultrafine nickel oxide particles (diameter < 4 nm) on multiwalled carbon nanotubes. The capacitance of the multiwalled carbon nanotubes/nickel oxide electrodes was … Show more

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Cited by 39 publications
(17 citation statements)
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“…where Sc (F g À1 ) is the gravimetric specic capacitance, Dt (s) is the galvanostatic discharge time, DV (V) is the potential window, m (g) is the mass of the active material, and I (A) is the response current. 28,29 . We nd that sample crystallinity increases with increasing calcination temperature for the same calcination time.…”
Section: Electrochemical Measurementsmentioning
confidence: 99%
“…where Sc (F g À1 ) is the gravimetric specic capacitance, Dt (s) is the galvanostatic discharge time, DV (V) is the potential window, m (g) is the mass of the active material, and I (A) is the response current. 28,29 . We nd that sample crystallinity increases with increasing calcination temperature for the same calcination time.…”
Section: Electrochemical Measurementsmentioning
confidence: 99%
“…Nevertheless, the intrinsic high electrical resistances of nickel oxides restrict their charge-discharge rate in a higher current density which is adverse for high-power energy storage applications. Based on this consideration, many researchers have fabricated a mass of composite materials by adding the highconductivity carbon-based materials, such as three-dimensional carbon nanotube networks supported nickel oxide [5] , carbon nanotubes/NiO nanocomposites [6] , microtubular carbonized kapok fiber/NiO composites [7] . Although these composites can improve the electrical conductivity to some extent, the effect is still unsatisfactory.…”
Section: Introductionmentioning
confidence: 99%
“…Among those metal oxides, NiO is considered to be one of the most attractive materials due to its good redox activity and high theoretical specific capacitance (2584 F g −1 ) 24 . For high-performance supercapacitors, a wide variety of hierarchical NiO micro/nanostructures, including nanosheets, nanotubes, hollow microspheres, flower-like microspheres have been investigated 24 25 26 27 . Although great progress has been made, it is still a great challenge to make a balance between excellent pseudo capacitive performance and simplicity of the synthetic pathway of NiO.…”
mentioning
confidence: 99%