Electrodeposition Silver(i) Selenide From Aqueuos Thiocyanate Solutions
V. V. Kuznetsov,
E. A. Tyagneryov,
A. V. Kapustin
et al.
Abstract:Electrodeposition of silver(I) selenide possessing pronounced thermoelectric properties was carried out from aqueous solutions containing thiocyanate complexes of silver(I) and Se (IV) compounds at pH 4.7. Ag2Se is formed at cathode potentials more negative than –0.9 V (s.h.e.). The obtained coatings were characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray phase analysis (XPA), and atomic force microscopy (AFM). The stoichiometry of the cathode deposit is close to… Show more
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