Electrodeposition of Ti from TiCl4 in the ionic liquid l-methyl-3-butyl-imidazolium bis (trifluoro methyl sulfone) imide at room temperature: study on phase formation by in situ electrochemical scanning tunneling microscopy

Mukhopadhyay, Indrajit; Aravinda, C. L.; Borissov, Dimitar; Freyland, W.

doi:10.1016/j.electacta.2004.07.052

Cited by 101 publications

(70 citation statements)

References 16 publications

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“…This is because most air-stable ILs show a large electrochemical window and negligible vapor pressure. Sub-micrometer to micrometer-ordered deposits of pure metals and semiconductors, such as Li, [143][144][145][146][147] Na, [147] K, [146,147] Cs, [148][149][150] Sr, [149] Mg, [151][152][153][154] Mn, [155][156][157][158][159] Ti, [160,161] Ta, [162,163] La, [164] Se, [165] In, [165] Ge, [166][167][168] and Si [169][170][171][172][173][174][175] have been electrodeposited in IL systems. In particular, Si deposition shows great promise for the development of novel technological process.…”

Section: Electrodeposition Of Metallic/semiconducting Materialsmentioning

confidence: 99%

New Frontiers in Materials Science Opened by Ionic Liquids

et al. 2010

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Ionic liquids (ILs) including ambient-temperature molten salts, which exist in the liquid state even at room temperature, have a long research history. However, their applications were once limited because ILs were considered as highly moisture-sensitive solvents that should be handled in a glove box. After the first synthesis of moisture-stable ILs in 1992, their unique physicochemical properties became known in all scientific fields. ILs are composed solely of ions and exhibit several specific liquid-like properties, e.g., some ILs enable dissolution of insoluble bio-related materials and the use as tailor-made lubricants in industrial applications under extreme physicochemical conditions. Hybridization of ILs and other materials provides quasi-solid materials, which can be used to fabricate highly functional devices. ILs are also used as reaction media for electrochemical and chemical synthesis of nanomaterials. In addition, the negligible vapor pressure of ILs allows the fabrication of electrochemical devices that are operated under ambient conditions, and many liquid-vacuum technologies, such as X-ray photoelectron spectroscopy (XPS) analysis of liquids, electron microscopy of liquids, and sputtering and physical vapor deposition onto liquids. In this article, we review recent studies on ILs that are employed as functional advanced materials, advanced mediums for materials production, and components for preparing highly functional materials.

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Section: Electrodeposition Of Metallic/semiconducting Materialsmentioning

confidence: 99%

New Frontiers in Materials Science Opened by Ionic Liquids

et al. 2010

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“…Nun könnte man annehmen, dass, wenn das sehr reaktive Lithium elektrochemisch zugänglich ist, auch andere reaktive Elemente leicht abgeschieden werden können wie Magnesium, Titan oder Tantal. In der Tat gibt es in der Literatur mehrere Berichte zur Abscheidung von Magnesium [17 -19] und Titan [20]. Nach unseren eigenen Erfahrungen wird Magnesium allerdings nicht als reine Phase erhalten [21] und anstelle von Titan werden eher Subhalogenide produziert [22].…”

Section: Publizierte Paul Walden Im Bulletin De L'académie Impérialeunclassified

Ionic Liquids for Electrochemical Deposition: Prospects and Challenges

Endres¹

2011

Chemie Ingenieur Technik

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Ionic Liquids for Electrochemical Deposition: Prospects and ChallengesIn this article the prospects and challenges of ionic liquids for electrodeposition processes are discussed. Despite wide electrochemical windows their electrochemical behavior is surprisingly complicated. They can influence the deposition process, and on solid surfaces solvation layers are formed which are that strongly adsorbed, that they can be probed by atomic force microscopy. Ionic liquids influence electrochemical reactions which might have prospects for an application driven electrochemistry.

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“…The application studies of ILs have been proposed varying from precious metal processing [29][30][31][32][33][34][35][36][37][38][39][40] to mineral leaching [41][42][43][44]; however, very few have come to practical fruition although several are at a pilot scale [45][46][47]. Except some technical diiculties that are hard to solve at our present state of knowledge [48], the relatively prohibitive high cost of ILs is also a main reason for delaying their industrial application [44].…”

Section: Why Use Ils As Electrodeposition Additives and Corrosion Inhmentioning

confidence: 99%

Ionic Liquids as Electrodeposition Additives and Corrosion Inhibitors

Zhang¹,

Ye²

2017

Progress and Developments in Ionic Liquids

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Ionic liquids (ILs) are molten salts with a melting point of 100°C or below and solely consist of cations and anions. As a kind of novel green solvent, ILs have been obtained broad and deep investigations, and enormous progresses in various ields have been made during the recent 20 years. Despite the fact that the application studies of ILs have been proposed in various ields, no processes have yet been developed to an industrial scale. However, the main interests are still focused on their industrial applications. In this chapter, two perspective applications of ILs in electrochemical ields including additives for metal electrodeposition and inhibitors for metal anti-corrosion were introduced.

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Electrodeposition of Ti from TiCl4 in the ionic liquid l-methyl-3-butyl-imidazolium bis (trifluoro methyl sulfone) imide at room temperature: study on phase formation by in situ electrochemical scanning tunneling microscopy

Cited by 101 publications

References 16 publications

New Frontiers in Materials Science Opened by Ionic Liquids

New Frontiers in Materials Science Opened by Ionic Liquids

Ionic Liquids for Electrochemical Deposition: Prospects and Challenges

Ionic Liquids as Electrodeposition Additives and Corrosion Inhibitors

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