Electrodeposition of palladium from palladium(II) acetylacetonate in an amide-type ionic liquid

Yoshii, Kazuki; Oshino, Yosuke; Tachikawa, Naoki; Toshima, Kazunobu; Katayama, Yasushi

doi:10.1016/j.elecom.2015.01.003

Cited by 34 publications

(25 citation statements)

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“…[14][15][16] We have reported that the metal complexes with acac ¹ , such as Pd(acac) 2 and Pt(acac) 2 , are stable in TFSA ¹ -based ionic liquids. [17][18][19] In the present study, the redox properties of Fe(acac) 3 were investigated in BMPTFSA.…”

Section: Introductionmentioning

confidence: 99%

Redox Reaction of Tris(acetylacetonato)iron(III) Complex in an Amide-type Ionic Liquid

et al. 2018

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The redox reaction of tris(acetylacetonato)iron(III) (Fe(acac) 3 ) on a glassy carbon electrode was investigated in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA). A one-electron transfer redox reaction of [Fe(acac) 3 ] 0/− showed the relatively negative potential of −1.4 V vs. Ag|Ag(I). The diffusion coefficient of Fe(acac) 3 estimated by chronoamperometry was (1.4 + 0.1) × 10 −7 cm 2 s −1 . The redox properties examined in this study suggested that the redox reaction of [Fe(acac) 3 ] 0/− can be utilized in the negative half-cell reaction of redox flow batteries.

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Section: Introductionmentioning

confidence: 99%

Redox Reaction of Tris(acetylacetonato)iron(III) Complex in an Amide-type Ionic Liquid

et al. 2018

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“…Different carboxylates allow for the tuning of the IL properties. Acetylacetonate-based ILs could be used for selective metal extraction [33,34]. Sulfonate anions allow for the extraction of hydrocarbons [35], and have potential applications in batteries [36].…”

Section: Ionic Liquid Librarymentioning

confidence: 99%

The Ionic Liquid Property Explorer: An Extensive Library of Task-Specific Solvents

Venkatraman

Evjen

Lethesh

2019

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Ionic liquids have a broad spectrum of applications ranging from gas separation to sensors and pharmaceuticals. Rational selection of the constituent ions is key to achieving tailor-made materials with functional properties. To facilitate the discovery of new ionic liquids for sustainable applications, we have created a virtual library of over 8 million synthetically feasible ionic liquids. Each structure has been evaluated for their-task suitability using data-driven statistical models calculated for 12 highly relevant properties: melting point, thermal decomposition, glass transition, heat capacity, viscosity, density, cytotoxicity, CO 2 solubility, surface tension, and electrical and thermal conductivity. For comparison, values of six properties computed using quantum chemistry based equilibrium thermodynamics COSMO-RS methods are also provided. We believe the data set will be useful for future efforts directed towards targeted synthesis and optimization.

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“…However, chemical reduction has limitations because of the finite strength of the reducing agents. Recently, Katayama et al demonstrated that MNPs can be formed via electrolysis in ILs [10][11][12]. Theoretically, this approach can be developed to be a universal method for MNP preparation because the reducing strength was controlled by the applied potential but limited by the electrochemical window of the electrolytes; ILs are thus very suitable electrolytes because of their wide electrochemical window.…”

Section: Introductionmentioning

confidence: 98%

Electrochemical formation of palladium nanoparticles in a salicylate-based hydrophilic ionic liquid: The effect of additives on particle morphology and electrochemical behavior

Tang

Kao

et al. 2016

Electrochemistry Communications

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Electrodeposition of palladium from palladium(II) acetylacetonate in an amide-type ionic liquid

Cited by 34 publications

References 24 publications

Redox Reaction of Tris(acetylacetonato)iron(III) Complex in an Amide-type Ionic Liquid

Redox Reaction of Tris(acetylacetonato)iron(III) Complex in an Amide-type Ionic Liquid

The Ionic Liquid Property Explorer: An Extensive Library of Task-Specific Solvents

Electrochemical formation of palladium nanoparticles in a salicylate-based hydrophilic ionic liquid: The effect of additives on particle morphology and electrochemical behavior

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