Electrode particulate materials for advanced rechargeable batteries: A review

Ma, Mingyang; Du, Miao; Liu, Na; Lü, Hong‐Yan; Yang, Jialin; Hao, Zelin; Guo, Jin‐Zhi; Wu, Xing‐Long

doi:10.1016/j.partic.2023.05.006

Cited by 6 publications

(2 citation statements)

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“…CBD,e,eff e (12) where σ CBD,e,eff is the effective electronic conductivity in porous CBD, which can be determined by = CBD,e,eff CBD e CBD (13) Here, σ e is the electrical conductivity of the conductive binder.…”

Section: Equations In Thementioning

confidence: 99%

“…In the last three decades, a great number of investigations have been done to improve the energy density and power density of LiBs, including developing new electrode materials and optimizing electrode structure. − Among these efforts, optimizing the electrode structure can enhance energy and power densities without changing the material composition and thus becomes a very effective method in improving LiB performance. Bae et al improved the electrode kinetics by using different distributions of porosity at multiple length scales of the electrode that reduce pore network tortuosity and maximize power density.…”

Section: Introductionmentioning

confidence: 99%

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Impact of Active Particle in Lithium-Ion Battery Probed by a Microstructure Resolved Model

Akbar,

Weng,

Zhang

et al. 2024

Ind. Eng. Chem. Res.

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For an electrode of lithium-ion batteries (LiBs), packing active particles yields a very complex microstructure that largely affects the battery performance. This work develops and validates a 3D microstructure-resolved model to study the influence of the active particle size distribution, particle shape, and particle packing configuration. The results show that mixing large and small particles in a random manner can increase the volume fraction of active materials, leading to the highest energy density when the diffusion limitation in the electrolyte is weak. A layered manner with small particles near the separator gives the highest energy density when the diffusion limitation in the electrolyte is severe. A wide particle size distribution deteriorates the performance of LiBs, as the number of large particles increases, and these particles are difficult for the intercalation of lithium. The effects of particle size distribution would not be qualitatively but quantitatively changed by the diffusion limitation in the electrolyte. Besides, the particle shape with a small sphericity is beneficial for improving energy density due to the shorter diffusion path. These results should serve to guide the optimal design of LiB electrodes with high performance.

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Section: Equations In Thementioning

confidence: 99%