“…The term viologen originally referred to quaternary 4,4 ′ -bipyridinium salts, in which the nitrogen rings are directly connected; however, over time, it has started to be used for related compounds possessing more than two charged pyridyl rings or a conjugated moiety as a spacer between them, since such structures retain the peculiar properties of actual viologens [7]. Among these properties, the most useful one is probably represented by the presence of three reversible and stable redox states, often characterized by different colors, from which another typical behavior of viologens arises, that is, electrochromism [8,9]. This characteristic makes viologens and their analogues a convenient choice for a large number of optoelectronic and energy-related applications, including memory devices [10], molecular switches [11], photocatalysts for hydrogen evolution [12] and different types of batteries [13,14].…”