Abstract:Prussian Blue films were studied by in situ electrogravimetric and spectroelectrochemical methods during the electrochemical oxidation to the Prussian Yellow form. Spectroelectrochemical studies detected important absorbance changes during electrochemical experiments at 430 nm and 690 nm corresponding to the appearance of the yellow form and to the disappearance of the characteristic blue color. These changes of absorbance were well related with the voltammetric peaks. This redox process has also been studied … Show more
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