Electrochemistry of single molecules and biomolecules, molecular scale nanostructures, and low-dimensional systems

Abstract

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Perspective and Prospectus on Single-Entity Electrochemistry

“…These include electrodes that trap adsorbed molecules, scanned probes with more well-defined control of the small gap, and electrified nanopore formats. Such methods and more are considered in detail in recent comprehensive reviews of single molecule research which provide excellent perspectives on the field. − …”

Applicability of perturbed matrix method for charge transfer studies at bio/metallic interfaces: a case of azurin

“…Electron transfer reactions at bio/metallic interfaces play an important role not only in electrochemical techniques dealing with biomolecules such as protein film voltammetry or electrochemical scanning tunneling microscopy 1–4 but also in rapidly developing nanobioelectronic applications, e.g. , photovoltaic devices, biomolecular electronics, or biofuel cells.…”

Nanoscale Electrochemical Mapping

“…We also cover electrochemical-scanning tunneling microscopy (EC-STM), where there have been interesting developments in high-resolution electrochemical mapping and in determining changes in electrode structure in electrochemical processes, which has been the main traditional use of EC-STM. We note in passing, that there has been considerable progress in single molecule conductance and electrochemistry studies with EC-STM, as highlighted in recent reviews, , but this topic is beyond the scope of this article.…”