Electrochemistry of Prussian Blue. An in situ Moessbauer effect measurement

Itaya, Kingo; Ataka, Tatsuaki; Toshima, Shinobu; Shinohara, T.

doi:10.1021/j100210a033

Cited by 88 publications

(30 citation statements)

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“…The electron transfer mechanisms for modified electrode at 0.2 and 0.9 V in the presence of potassium electrolyte may be formulated as follows with assuming Fe III 4 ½Fe II ðCNÞ 6 3 formula for PB as reported previously [16,17,24,25]. Peak at 0.2V shows the the following reaction:…”

Section: Introductionmentioning

confidence: 99%

Electrochemical formation of Prussian blue films with a single ferricyanide solution on gold electrode

Abbaspour

Kamyabi

2005

Journal of Electroanalytical Chemistry

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Section: Introductionmentioning

confidence: 99%

Electrochemical formation of Prussian blue films with a single ferricyanide solution on gold electrode

Abbaspour

Kamyabi

2005

Journal of Electroanalytical Chemistry

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“…Neff on the surface of gold electrodes [10]. Some years later, in 1982 Itaya et al [3,[11][12][13][14] described a galvanostatic procedure to produce good and controlled quality PB films on different type of electrode substrate. In these works, it has been proved that some electrochemical properties are dependent on the rate of electrogeneration, obtaining narrower and sharper voltammetric peaks for the higher current deposited PB films.…”

Section: Introductionmentioning

confidence: 99%

Identification of electroactive sites in Prussian Yellow films

Agrisuelas

Garcı́a-Jareño

Moreno-Guerrero

et al. 2013

Electrochimica Acta

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Abstract.Prussian Blue films were electrogenerated on the surface of the transparent ITO electrodes. The electrochemical oxidation to the Prussian Yellow form was investigated by means of in situ voltammetry and Vis-NIR spectroscopic techniques. Changes of the whole spectra between 400 and 950 nm were analyzed and three characteristic wavelengths were selected to in situ follow the electrochemical changes of the films.Voltammetric peaks and absorbance derivative curves at these three wavelengths were deconvoluted and were interpreted such as the overlapping of different electrochemical processes. The correlation between these overlapped processes has allowed proposing three different electrochemical processes for the interpretation of the whole electrochemical response. One of these processes corresponds to the oxidation of

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“…The interpretation of the reaction that occurs in the iron hexametallocyanates at about 0.2 V positive of the SCE is the reduction of high-spin Fe 3 § to low-spin Fe 2 § as the potential is reduced, and the corresponding oxidation as the potential is increased has been established on the basis of in-situ Mtissbauer experiments [42].…”

Section: Electrochemical Behavior Of Prussian Bluementioning

confidence: 99%

Mixed-conductors with either cation or anion insertion

Huggins

1997

Ionics

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Abstract. It has been known for some 25 years that charge can be stored in some important battery electrodes by the insertion of ionic species from the electrolyte. Insertion reactions play an especially important role in current versions of lithium batteries, where lithium cations are typically the inserted species in both electrodes. Hydrogen cations (protons) are the guest species during the operation of both the Ni(OH)JNiOOH electrode and the "MnO2" electrode in aqueous systems.Whereas most attention has been given to materials in which the guest species are cations, it is also possible to have anion insertion into some crystal structures. Materials in which the structure can accommodate either cations or anions are especially interesting. The hexacyanometallates, with variations of the cubic ReO3 type structure with rather large intercell windows, represent an interesting example. They can accommodate a wide variety of guest ions of both charges. Cations can be inserted into the structure at relatively low potentials, and anions can be inserted at more positive potentials. A number of interesting features and properties of this family of materials are discussed.

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Electrochemistry of Prussian Blue. An in situ Moessbauer effect measurement

Cited by 88 publications

References 1 publication

Electrochemical formation of Prussian blue films with a single ferricyanide solution on gold electrode

Electrochemical formation of Prussian blue films with a single ferricyanide solution on gold electrode

Identification of electroactive sites in Prussian Yellow films

Mixed-conductors with either cation or anion insertion

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