Electrochemically Driven Transformation of Olivine LiFePO4 to Olivine NaFePO4 in Cells with Sodium Anode and Carbonate Electrolyte
Yurii Shmatok,
Nataliya Globa,
Vitalii Sirosh
et al.
Abstract:The direct electrochemical transformation of commercial LiFePO4 to NaxFePO4 olivine in a Na||LiFePO4 electrochemical cell with sodium electrolyte has been studied. Electrolytes containing 1 M of NaClO4 in ethylene carbonate (EC), dimethyl carbonate (DEC) and fluoroethylene carbonate (FEC) have been probed, and in the solvents with the ratio of EC:DMC:FEC = 0.4:0.5:0.1 by volume, maximal values of the specific capacity (113 mAh g‐1) with good cycling stability and maximal discharge currents are achieved upon so… Show more
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