International Conference on Science and Technology of Synthetic Metals 1994
DOI: 10.1109/stsm.1994.835367
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Electrochemical synthesis of poly(para-phenylene) and its electrical properties

Abstract: The effects of oxidant(ammonia persulfate)/aniline ratio and reaction temperature on the yield, oxidation state, solubility in NMP and the properties of the films made from NMP solution were studied. The yields of polyaniline reach a maximum when oxidant/aniline ratio equals to 1.25 and reaction temperature is -5 C. The solubilities of polyaniline base form also reach a maximum at oxidant/aniline ratio of 1.25 and reaction temperatures of -5 C and 0 C. The ratios of benzene ring and quinoid ring are the same f… Show more

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“…Its ICPs, which have low molecular weights and with modified chains, are soluble in many solvents [ 116 , 117 , 118 , 119 ]. They may be synthesized by electrochemical [ 120 ] and chemical methods [ 116 , 121 ], for example, polycondensation with the Suzuki coupling method or catalytic polymerization. PPP frequently shows linearly dichromic fluorescence [ 122 ].…”
Section: Synthesis Physicochemical and Biological Properties Of Cmentioning
confidence: 99%
“…Its ICPs, which have low molecular weights and with modified chains, are soluble in many solvents [ 116 , 117 , 118 , 119 ]. They may be synthesized by electrochemical [ 120 ] and chemical methods [ 116 , 121 ], for example, polycondensation with the Suzuki coupling method or catalytic polymerization. PPP frequently shows linearly dichromic fluorescence [ 122 ].…”
Section: Synthesis Physicochemical and Biological Properties Of Cmentioning
confidence: 99%
“…Its ICPs, which have low molecular weights and with modified chains, are soluble in many solvents [110], [111], [112], [113]. They may be synthesized by electrochemical [114] and chemical methods [110], [115], for example, polycondensation with the Suzuki coupling method or catalytic polymerization. PPP frequently shows linearly dichromic fluorescence [116].…”
Section: Electronically Conducting Polymers (Intrinsically Conductingmentioning
confidence: 99%