“…Rangelov (Ref 17) and Co(II), Ni(II), Cu(II), and Zn(II) with 2-acetylthiophene benzoylhydrazone (Ref 18) were reported to show appreciable corrosion inhibition properties for mild steel in 1 M HCl solutions. Generally, the metal complexes were reported to be more effective in inhibiting acidic corrosion than their respective ligands ( Ref 11,12,14,[16][17][18]. The increased efficiency of the metal complexes compared to their respective ligands has been attributed to the low water solubility, high molecular weight, and molecular planarity of the complexes ( Ref 2,17), and the stabilizing chelate effect of the ligands ( Ref 12).…”