Electrochemical Study of the Additive-Effect on Sn Electrodeposition in a Methansulfonate Acid Electrolyte

Long, Jin Ming; Zhu, Zhaohui; Guo, Zhu; Zhu, Xinping; Huang, Hui

doi:10.4028/www.scientific.net/amr.460.7

Cited by 2 publications

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References 6 publications

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“…This result was obtained with others additives 13,16 . This is caused by the adsorption of the additive on the working electrode surface [12][13][14][15][16] , which impeded the charge transfer 17,18 . To prevent the oxidation of the working electrode during cyclic voltammetry measurements, iron was replaced by copper working electrode.…”

Section: Chronopotentiometric Measurementsmentioning

confidence: 99%

Tin electrodeposition from sulfate solution containing a benzimidazolone derivative

2016

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Tin electrodeposition in an acidic medium in the presence of N,N’-1,3-bis-[N-3-(6-deoxy-3-O-methylD-glucopyranose-6-yl)-2-oxobenzimidazol-1-yl)]-2-tetradecyloxypropane as an additive was investigated in this work. The adequate current density and the appropriate additive concentration were determined by gravimetric measurements. Chronopotentiometric curves showed that the presence of the additive caused an increase in the overpotential of tin reduction. The investigations by cyclic voltammetry technique revealed that, in the presence and in absence of the additive, there were two peaks, one in the cathodic side attributed to the reduction of Sn2+ and the other one in the anodic side assigned to the oxidation of tin previously formed during the cathodic scan. The surface morphology of the tin deposits was studied by scanning electron microscopy (SEM) and XRD.

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