“…The thick electrolyte layer usually results in high ohmic resistance. Thus, more effort is focussed on high temperature operation for electrolyte-supported SOFCs in a bid to reduce the ohmic resistance [39].…”
A two-dimensional along the channel micro-scale isothermal model of a SOFC is developed and validated against experimental data and other simulated results from literature. The steady state behaviour of the cell was determined by numerical solution of the combined transport, continuity and kinetic equations. An important characteristic of the model is the consideration of the triple phase boundary as a distinct layer. The model is capable of predicting the cell performance including polarisation behaviour and power output. The model is used to study the effect of the support structure, geometric parameters and the effect of operating conditions on cell performance. Several parametric studies include the effect of operating conditions and geometric parameters on cell performance with a view to optimising the cell. The simulation results showed that the anode supported SOFC displayed the best performance with the activation and ohmic overpotentials being responsible for most of the voltage losses in the cell.
“…The thick electrolyte layer usually results in high ohmic resistance. Thus, more effort is focussed on high temperature operation for electrolyte-supported SOFCs in a bid to reduce the ohmic resistance [39].…”
A two-dimensional along the channel micro-scale isothermal model of a SOFC is developed and validated against experimental data and other simulated results from literature. The steady state behaviour of the cell was determined by numerical solution of the combined transport, continuity and kinetic equations. An important characteristic of the model is the consideration of the triple phase boundary as a distinct layer. The model is capable of predicting the cell performance including polarisation behaviour and power output. The model is used to study the effect of the support structure, geometric parameters and the effect of operating conditions on cell performance. Several parametric studies include the effect of operating conditions and geometric parameters on cell performance with a view to optimising the cell. The simulation results showed that the anode supported SOFC displayed the best performance with the activation and ohmic overpotentials being responsible for most of the voltage losses in the cell.
“…where F is the Faraday's constant, k e´´ the pre-exponential factor (which is 6.5410 11 -1 m -2 for the anode and 2.3510 11 -1 m -2 for the cathode [25]), i 0 the exchange current density, R the ideal gas constant, AV e the electrochemical active area-to-volume ratio and E a,e the activation energy (137 kJ/mol for the cathode and 140 kJ/mol for the anode [16]). The potential difference between the anode and the cathode current collectors corresponds to the total cell operating voltage.…”
Section: Ion and Electron Transport As Well As Electrochemical Reactionsmentioning
“…An activation energy (E a,e ) of 137 kJ/mol for the cathode and 140 kJ/mol for the anode are used by Patcharavorachot et al [20] and Aguiar et al [22] The heat generation by the electrochemical reactions and due to the losses through the activation, the ohmic and the concentration polarizations is given by [25]: (12) Here, i is the current density, is the ion/electron conductivity, Q h is the heat generation/consumption and S r is the entropy change of the electrochemical reactions, calculated from the data in [37] for the anode and the cathode TPBs, respectively.…”
Section: Ion and Electron Transport As Well As Electrochemical Reactionsmentioning
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