Abstract:This work describes the development of electrochemical sensors based on graphite–polyurethane composite (GPU) modified with aluminophosphate zeolite type 5 (AlPO‐5) and nickel (II) incorporated aluminophosphate type 5 (NiAlPO‐5), in order to evaluate their performance for determination of Cu2+ in ethanol biofuel. These electrodes were initially characterized by cyclic voltammetry. The obtained results revealed that the NiAlPO‐5 with Ni/Al ratio 0.5 presented the best response in terms of sensitivity, and peak … Show more
Fluorescent chemosensors based on 4-hydroxy cyclopentenones were synthesized by the base catalyzed reaction of 1,5-diphenyl-pentane-1,3,5-trione with benzil and thenil. The molecule obtained by the benzil reaction was found to be useful for the selective detection of Fe 3+ by fluorescence turn-off, while the molecule synthesized by the thenil reaction was useful for selective detection of Cu 2+ by fluorescent turn-on. Details of the synthesis, complexation mode, nature of binding, reversibility, and pH studies of the two sensors are discussed. The studies revealed that the sensors were suitable for determining Fe 3+ and Cu 2+ content in real water samples.
Fluorescent chemosensors based on 4-hydroxy cyclopentenones were synthesized by the base catalyzed reaction of 1,5-diphenyl-pentane-1,3,5-trione with benzil and thenil. The molecule obtained by the benzil reaction was found to be useful for the selective detection of Fe 3+ by fluorescence turn-off, while the molecule synthesized by the thenil reaction was useful for selective detection of Cu 2+ by fluorescent turn-on. Details of the synthesis, complexation mode, nature of binding, reversibility, and pH studies of the two sensors are discussed. The studies revealed that the sensors were suitable for determining Fe 3+ and Cu 2+ content in real water samples.
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