Electrochemical sensor based on molecularly imprinted polymer reduced graphene oxide and gold nanoparticles modified electrode for detection of carbofuran

Tan, Xuecai; Hu, Qi; Wu, Jiawen; Li, Xiaoyü; Li, Pengfei; Yu, Hua-Zhong; Li, Xiaoyan; Lei, Fuhou

doi:10.1016/j.snb.2015.05.048

Cited by 137 publications

(31 citation statements)

References 28 publications

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“…The polymerization around the template molecule was carried out with the presence of functional monomer (methyl acrylic acid) and cross-linker (ethylene glycol maleic rosinate acrylate). The LOD was 2.0 × 10 −8 mol/L [135]. …”

Section: Electrochemical Transductionmentioning

confidence: 99%

Imprinting Technology in Electrochemical Biomimetic Sensors

Frasco

Truta

Sales

et al. 2017

Sensors

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Biosensors are a promising tool offering the possibility of low cost and fast analytical screening in point-of-care diagnostics and for on-site detection in the field. Most biosensors in routine use ensure their selectivity/specificity by including natural receptors as biorecognition element. These materials are however too expensive and hard to obtain for every biochemical molecule of interest in environmental and clinical practice. Molecularly imprinted polymers have emerged through time as an alternative to natural antibodies in biosensors. In theory, these materials are stable and robust, presenting much higher capacity to resist to harsher conditions of pH, temperature, pressure or organic solvents. In addition, these synthetic materials are much cheaper than their natural counterparts while offering equivalent affinity and sensitivity in the molecular recognition of the target analyte. Imprinting technology and biosensors have met quite recently, relying mostly on electrochemical detection and enabling a direct reading of different analytes, while promoting significant advances in various fields of use. Thus, this review encompasses such developments and describes a general overview for building promising biomimetic materials as biorecognition elements in electrochemical sensors. It includes different molecular imprinting strategies such as the choice of polymer material, imprinting methodology and assembly on the transduction platform. Their interface with the most recent nanostructured supports acting as standard conductive materials within electrochemical biomimetic sensors is pointed out.

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Section: Electrochemical Transductionmentioning

confidence: 99%

Imprinting Technology in Electrochemical Biomimetic Sensors

Frasco

Truta

Sales

et al. 2017

Sensors

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“…These materials are sometimes referred to as molecularly imprinted polymers (MIPs) . The molecular recognition property makes MIPs suitable for sensor fabrication, as reported in literature over many years . MIP‐based sensors can identify structures ranging from small to large molecules, proteins, or even whole microorganisms such as bacteria or viruses .…”

Section: Figurementioning

confidence: 99%

“…[6] The molecular recognition property makes MIPs suitable for sensor fabrication,a sr eported in literature over many years. [7][8][9][10][11] MIPbased sensors can identify structures ranging from small to large molecules, proteins, or even whole microorganisms such as bacteria or viruses. [12,13] In case of virus MIP biosensors, the main applicationsa re virus detection, classification, or virus bindinga ssays.…”

mentioning

confidence: 99%

Small‐Molecule Dengue Virus Co‐imprinting and Its Application as an Electrochemical Sensor

et al. 2017

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Polymers can be synthesized to recognize small molecules. This is achieved by introducing the target molecule during monomer self‐assembly, where they can be incorporated during cross‐linking polymerization. Following additional pre‐processing, the material obtained can then be applied as a sensing layer for these molecules in many applications. The sensitivity of the polymers depends on the “active sites” imprinted on the surface. Increasing the number of active sites on the polymers surface can be achieved by using nanoparticles as a platform to support and concentrate the molecules for imprinting. In this work, we report the first use of dengue virus as a supporting nanoparticle to make for a more effective polymer composite sensor for the detection of bisphenol A (BPA), which is an environmental contaminant. The dengue virus has a nanoparticle size of around 100 nm and its surface provides regions where lipids and hydrophobic compounds can bind, making it an ideal support. The mixing of BPA with dengue prior to monomer self‐assembly led to imprinted polymer surfaces with much higher density BPA binding sites and a limit of detection of 0.1 pm. We demonstrate that a BPA–dengue co‐imprinting polymer composite sensor shows a very high sensitivity for BPA, but with lower production costs and technical requirements than other comparable methods.

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“…These sensors include glassy carbon electrode (GCE) modified with MWCNTs/cobalt phthalocyanine and graphene oxide‐ionic liquid composite low silica X zeolite modified carbon paste electrode (CPE) and graphene‐modified boron‐doped diamond electrode for detection of CBR in the real samples. Furthermore, Tan et al., designed a novel molecularly imprinted sensor based on GCE decorated by reduced graphene oxide and gold nanoparticles (rGO@Au) to monitoring of CBF in real vegetable samples Wang et al., for the first time, reported a new electrochemical sensor based on CoO nanoparticle‐decorated reduced graphene oxide (rGO) modified GCE for the simultaneous detection of CBF and CBR . Also, a nanocarbon black‐based screen printed sensor was developed by Della Pelle et al.…”

Section: Introductionmentioning

confidence: 98%

Design and Application of a Non‐enzymatic Sensor Based on Metal‐organic Frameworks for the Simultaneous Determination of Carbofuran and Carbaryl in Fruits and Vegetables

Soltani‐Shahrivar

Karimian²,

Fakhri

et al. 2019

Electroanalysis

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A novel, stable and sensitive non‐enzymatic sensor was developed with metal‐organic frameworks (MOFs) that have attracted great attention in electrochemical sensors applications in recent years. The pore structures of MIL (Fe)‐101 and MIL (Fe)‐53 are the families of MOFs that were constructed via a simple solvothermal procedure. The 35MIL‐101(Fe)‐reduced graphene oxide nanocomposite has been used for modification of glassy carbon electrode for the determination of carbofuran (CBF) and carbaryl (CBR). The porosity of the composites increased the voltammetric responses significantly for CBF and CBR in a mixed solution that makes the simultaneous determination of both carbamate pesticides possible. Characterization of MIL (Fe)‐101 and MIL (Fe)‐53 were performed with FT‐IR, XRD, BET and SEM. Finally, the introduced sensor under the optimal conditions showed low detection limits of 1.2 and 0.5 nM within the linear ranges of 5.0–200.0 nM and 1.0–300.0 nM for CBF and CBR, respectively. The non‐enzymatic sensor was successfully used to monitoring of carbamates residue in vegetable and fruit samples.

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Electrochemical sensor based on molecularly imprinted polymer reduced graphene oxide and gold nanoparticles modified electrode for detection of carbofuran

Cited by 137 publications

References 28 publications

Imprinting Technology in Electrochemical Biomimetic Sensors

Imprinting Technology in Electrochemical Biomimetic Sensors

Small‐Molecule Dengue Virus Co‐imprinting and Its Application as an Electrochemical Sensor

Design and Application of a Non‐enzymatic Sensor Based on Metal‐organic Frameworks for the Simultaneous Determination of Carbofuran and Carbaryl in Fruits and Vegetables

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