Electrochemical Sensing and Photoelectrodegradation of Pentachlorophenol using Co‐, Mn‐ and Zn‐Porphyrins
Mbulelo Jokazi,
Tebello Nyokong
Abstract:In this work, we present Zn, CoII, and MnIII metalated meso‐tetra‐[4‐(methylthio) phenyl] porphyrin ([Zn(TMtPP)], [CoII(TMtPP], and [MnIII(TMtPP)Cl]) as electrocatalysts and photoelectrocatalysts for electrochemical detection and photoelectrocatalytic degradation of pentachlorophenol (PCP). The complexes were characterized using UV‐visible spectroscopy, mass spectroscopy, and elemental analysis. Proton nuclear magnetic resonance (1H NMR) studies were only conducted for the Zn derivative. The electrochemical de… Show more
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