Electrochemical quartz crystal microbalance study of the electrodeposition mechanism of molybdenum oxide thin films from peroxo-polymolybdate solution

Cathodic electrodeposition of mixed molybdenum–selenium oxides

“…[31][32][33]41]. The charge measured (Q) was assumed to be directly proportional to the amount of species deposited in moles (N) in accordance with Faraday's Law (Q = nFN).…”

Intermediate molybdenum oxides involved in binary and ternary induced electrodeposition

“…Mo V transitions [15]. The E band shifted towards lower wavelengths as the pH increased, indicating again that a more reduced molybdenum oxide film was gradually deposited on the electrode, probably as a consequence of a minor proton insertion [15].…”

“…These oxide films are usually obtained by vacuum evaporation [11], sputtering [8], chemical vapour deposition [6,7,12] and anodic oxidation [13]. In recent years, the preparation of these materials by electrodeposition has attracted the interest of several investigators [9,14,15], but little work has been done regarding to the characteristics of their electroformation.…”

Structurally and mechanically tunable molybdenum oxide films and patterned submicrometer structures by electrodeposition

“…McEvoy and Stevenson described the cathodic electrodeposition of MoO 3 from acidic peroxo-polymolybdate solutions onto indium-doped tin oxide (ITO) electrode [27]. The same authors deeply investigated the mechanism of molybdenum oxides deposition using different tools, namely chronocoulometry and quartz crystal microbalance techniques [28,29]. The authors showed that a graded reduction of molybdenum precursors toward amorphous hydrates of non-stoichiometric, mixed-valent molybdenum oxides takes place from acidic peroxo-polymolybdate solutions.…”