Electrochemical Performance and Degradation Analysis of an SOFC Short Stack Following Operation of More than 100,000 Hours

Abstract

From August 2007 to January 2019, a two-layer solid oxide fuel cell (SOFC) short stack of a planer design with zirconia-based, anode-supported cells (ASC) and ITM interconnectors (with 26% chromium content) was tested with hydrogen and compressed air at a furnace temperature of 700°C for more than 100,000 hours, of which ∼93,000 were in constant current mode, with a current density of 0.5 Acm−2 and with a fuel utilization of 40%. The calculated voltage degradation rate slowly decreased, from ∼8.0 mV/kh (∼1.0%/kh) for the first 40,000 h to ∼1.4 mV/kh (∼0.2%/kh) for the subsequent operation under load, indicating different dominating degradation mechanisms. The average voltage and area-specific resistance (ASR) degradation rates for the complete operating period under electrical load were 0.5%/kh and 2.5%/kh, respectively. Electrochemical impedance spectroscopy (EIS) was also implemented at the end of the testing period for the purpose of electrochemical characterization and a degradation analysis. The post-mortem analysis of the stack is currently in preparation. In this study, the performance and degradation behavior of the stack and cells are analyzed and discussed on the basis of the electrochemical measurements collected.

Electronic and ionic effects of sulphur and other acidic adsorbates on the surface of an SOFC cathode material

“…[1][2][3][4] While cell performance steadily increases and new materials are being developed to drive SOFCs towards lower operating temperatures, [5][6][7][8][9] a key hindrance for a wide applicability lies in their inherent susceptibility to performance degradation, in particular with regard to the oxygen exchange reaction (OER) on the cathode side. [10][11][12] Apart from morphological degradation processes such as delamination or cracking, cathode degradation factors can be broadly divided into two categories: (1) materials change chemically under operating conditions, affecting the catalytic activity of the surface (e.g. Sr segregation in Sr-containing perovskites); [13][14][15] (2) environmental impurities (e.g.…”

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“…Table 3 shows details of MFCs, operation conditions and stack designs of several stacks, which are used for the validation of models. The temperature values in Table 3 are taken according to thermocouples that was roughly placed 10 mm-deep into the intermediate interconnector (details of the location can be found in reference [55]).…”

Electrification of gasification-based biomass-to-X processes – a critical review and in-depth assessment

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