2017
DOI: 10.5599/jese.406
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Electrochemical oscillation of vanadium ions in anolyte

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Cited by 7 publications
(6 citation statements)
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“…Vanadium existed in low valence as V­(III) and V­(IV) in the residue, as seen from Figure . During the leaching process, the H 2 O molecule or OH – was oxidized to • OH by the electric field. ,, Then it migrated toward the bulk solution and reacted with the low-valence vanadium in the residue and oxidized it to high-valence vanadium (V­(V)), which highly dissolved in the alkaline medium. The reactions during the leaching process can be expressed by the model shown in Figure and the equations as follows , where MO x stands for the metal electrode.…”
Section: Resultsmentioning
confidence: 99%
“…Vanadium existed in low valence as V­(III) and V­(IV) in the residue, as seen from Figure . During the leaching process, the H 2 O molecule or OH – was oxidized to • OH by the electric field. ,, Then it migrated toward the bulk solution and reacted with the low-valence vanadium in the residue and oxidized it to high-valence vanadium (V­(V)), which highly dissolved in the alkaline medium. The reactions during the leaching process can be expressed by the model shown in Figure and the equations as follows , where MO x stands for the metal electrode.…”
Section: Resultsmentioning
confidence: 99%
“…Oscillating reactions are also known in electrochemistry, e.g. spontaneous oscillations of electrode potential [8], the Belousov-Zhabotinsky, Bray-Liebhafsky, Briggs-Rauscher reactions [9], [10] or biochemical peroxidase-oxidase and liquid membrane oscillators [8], [11]. The formation of hydronium and carbonate ions H 3 O + , HCO 3 and CO 3 2from carbon dioxide in the aqueous phase can also be considered from the viewpoint of coupled oscillators.…”
Section: Introductionmentioning
confidence: 99%
“…At present, the Belousov-Zhabotinsky (B-Z) oscillation reaction is most widely used in analysis and detection, followed by the copper ion oscillation system (Alfifi et al, 2016;Luiz Fernando Oliveira Maia et al, 2019;Nawabi et al, 2019;Ullah et al, 2019). There are also Bray-Liebhafsky oscillation reaction, Briggs-Rauscher oscillation reaction, peroxidaseoxidase biochemical oscillator (peroxidase-oxidase oscillation system), and liquid membrane oscillator (Mukouyama et al, 2016;Bai et al, 2017;Peng et al, 2017;Chan and Dow, 2019;Ding et al, 2019). The basis for applying chemical oscillation reaction to analysis and detection is that the substance to be tested can interfere with the oscillation reaction.…”
Section: Introductionmentioning
confidence: 99%