1995
DOI: 10.1016/0257-8972(95)02545-6
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Electrochemical impedance spectroscopy of PVD-TiN coatings on mild steel and AISI316 substrates

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Cited by 19 publications
(20 citation statements)
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“…3(b) represents conduction through the alkane chain length of the monolayer [55]. Hence, R IM can be used to quantify the quality of the monolayer, as has been applied previously to characterize SAMs on Au [36,37], and this is based on prior work of coatings on metals [56,57]. The fitting results obtained from the application of the two equivalent circuit models from Fig.…”
Section: Impedance Modelmentioning
confidence: 98%
“…3(b) represents conduction through the alkane chain length of the monolayer [55]. Hence, R IM can be used to quantify the quality of the monolayer, as has been applied previously to characterize SAMs on Au [36,37], and this is based on prior work of coatings on metals [56,57]. The fitting results obtained from the application of the two equivalent circuit models from Fig.…”
Section: Impedance Modelmentioning
confidence: 98%
“…The total polarization resistance (R p ) is taken as the sum of all resistances obtained from the EIS results [31,33,35,38,40]:…”
Section: Electrochemical Impedance Spectroscopy Measurementsmentioning
confidence: 99%
“…The case is even more severe if the coating systems are exposed to an aggressive environment, for example, a Cl À -containing solution due to the aggressive effects of chloride ion in promoting pitting corrosion. On further increasing the immersion time, the impedance enhanced slightly after 48 h immersion as compared to 24 h immersion induced by the blocking of pinholes by corrosion products [20] from the solution/substrate interface. That is, after 48 h immersion, the corrosion products plugged in the pinholes and the electric resistances of corrosion products were higher than that of solution.…”
Section: Discussionmentioning
confidence: 86%