2000
DOI: 10.1149/1.1393249
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Electrochemical Characterization of the Nanoporous Honeycomb Diamond Electrode as an Electrical Double-Layer Capacitor

Abstract: Electrochemical properties of nanoporous honeycomb diamond electrodes in an aqueous electrolyte were investigated. Highly ordered honeycomb diamond structures were fabricated by etching the microwave plasma-deposited diamond films using an oxygen plasma. The diamond honeycomb exhibited a wide electrochemical potential window (ca. 2.5 V), similar to the unetched diamond film. From impedance measurements, the capacitance of the diamond honeycomb film was found to be 1.97 ϫ 10 Ϫ3 F cm Ϫ2 (geometric area), which i… Show more

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Cited by 112 publications
(74 citation statements)
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“…The electrodes capacitance curve, in the studied potential range, presented a similar behavior to that observed in Figure 8, in which the capacitance increases as a function of the potential. These results also showed good agreement with the values found by Honda and coworkers 31 . For their nanohoneycomb diamond electrode, the capacitance value at 1.0 V × Ag/AgCl was 190 μF.cm -2 , 15 times greater than that for their diamond electrode.…”
Section: Resultssupporting
confidence: 92%
See 1 more Smart Citation
“…The electrodes capacitance curve, in the studied potential range, presented a similar behavior to that observed in Figure 8, in which the capacitance increases as a function of the potential. These results also showed good agreement with the values found by Honda and coworkers 31 . For their nanohoneycomb diamond electrode, the capacitance value at 1.0 V × Ag/AgCl was 190 μF.cm -2 , 15 times greater than that for their diamond electrode.…”
Section: Resultssupporting
confidence: 92%
“…They attributed the high capacitance values to the formation of highly ordered porous structure, as well as, to the surface oxidation. The BDUND/PS electrodes obtained in this study showed a capacitance value about 30 times greater than that of nanohoneycomb diamond obtained by Honda et al 31 . …”
Section: Resultscontrasting
confidence: 65%
“…23 In addition, two peaks at 500 cm ¹1 and 1230 cm ¹1 can be interpreted as fraction of carbon disorder due to the presence of boron-doped were observed. 15,24 XPS (JEOL JPS-9010 TR photoelectron/spectrometer) was used to characterize the chemical composition at the electrode surface.…”
Section: ¹1mentioning
confidence: 99%
“…Honda and coworkers demonstrated the suitability of BDD nanoporous honeycomb electrodes for the development of aqueous electrochemical capacitors [54]. Nanoporous honeycomb diamond films were fabricated from microwave plasma chemical vapor deposited diamond films by oxygen plasma etching through an alumina mask.…”
Section: Bdd-electrochemical Capacitorsmentioning
confidence: 99%