2023
DOI: 10.1002/celc.202201117
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Electrochemical Characterization of Charge Storage at Anodes for Sodium‐Ion Batteries Based on Corncob Waste‐Derived Hard Carbon and Binder

Abstract: Sodium‐ion batteries (SIBs) represent a potential alternative to lithium‐ion batteries in large‐scale energy storage applications. To improve the sustainability of SIBs, the utilization of anode carbonaceous materials produced from biomass and the selection of a bio‐based binder allowing an aqueous electrode processing are fundamental. Herein, corncobs are used as raw material for the preparation of hard carbon and it is also used as cellulose sources for the synthesis of carboxymethyl cellulose (CMC) binder. … Show more

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Cited by 11 publications
(4 citation statements)
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References 92 publications
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“…Given the advantages of affordability and environmental friendliness, it is highly desirable to employ cellulose derivatives as binders, particularly when sourced directly from waste food products. For example, corncobs can serve as the raw materials for both carbon production and the creation of a sodium carboxymethylcellulose binder [ 173 ]. The resulting carbon material demonstrates appropriate interlayer spacing and a favourable surface area, enabling partial bulk insertion and interfacial adsorption of sodium ions.…”
Section: Energy Storage Applications Of Food Waste Derived Porous Car...mentioning
confidence: 99%
“…Given the advantages of affordability and environmental friendliness, it is highly desirable to employ cellulose derivatives as binders, particularly when sourced directly from waste food products. For example, corncobs can serve as the raw materials for both carbon production and the creation of a sodium carboxymethylcellulose binder [ 173 ]. The resulting carbon material demonstrates appropriate interlayer spacing and a favourable surface area, enabling partial bulk insertion and interfacial adsorption of sodium ions.…”
Section: Energy Storage Applications Of Food Waste Derived Porous Car...mentioning
confidence: 99%
“…In short, the electrochemical properties brought by different locations of the same plant are also different in terms of self‐opening. The pore volume of the material prepared by Bottoni [118] et al . using corncob was about 1.6 times higher than that of the hard carbon material prepared by Ou [37] et al .…”
Section: Designing Preferred Structures Of Plant‐based Hard Carbon Vi...mentioning
confidence: 99%
“…Song et al [38] utilized corn cob as raw material to prepare biomass carbon at different pyrolysis temperatures (1000 °C, 1200 °C, 1400 °C, and 1600 °C), the prepared sample showed higher graphitization and an increase in the number of layers as the pyrolysis temperature increased. Luca et al [39] used a heating rate of 10°C/min to pyrolyze the corn cob at 950 °C. The biomass carbon was used as the anode material for the battery, while carboxymethyl cellulose extracted from the corn cob chemically be used as a binder in the battery preparation.…”
Section: High-temperature Carbonizationmentioning
confidence: 99%