Electrochemical behavior of organic molecules containing sulfur

Simonet, Jacques

doi:10.1002/9780470034408.ch10

PATAI'S Chemistry of Functional Groups

1993

DOI: 10.1002/9780470034408.ch10

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Electrochemical behavior of organic molecules containing sulfur

Jacques Simonet

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Cited by 10 publications

References 103 publications

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Electron‐Poor Thiophene 1,1‐Dioxides: Synthesis, Characterization, and Application as Electron Relays in Photocatalytic Hydrogen Generation

Tsai

Chirdon

Kagalwala

et al. 2015

Chemistry A European J

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The synthesis and characterization of electron-poor thiophene 1,1-dioxides bearing cyanated phenyl groups are reported. The electron-accepting nature of these compounds was evaluated by cyclic voltammetry, and highly reversible and facile reductions were observed for several derivatives. Moreover, some of the reduced thiophene dioxides form colorful anions, which were investigated spectroelectrochemically. Photoluminescence spectra of the electron-deficient sulfones were measured in CH2 Cl2, and they emit in the blue-green region with significant variation in the quantum yield depending on the aryl substituents. By expanding the degree of substitution on the phenyl rings, quantum yields up to 34 % were obtained. X-ray diffraction data are reported for two of the thiophene 1,1-dioxides, and the electronic structure was probed for all synthesized derivatives through DFT calculations. The dioxides were also examined as electron relays in a photocatalytic water reduction reaction, and they showed potential to boost the efficiency.

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Electron‐Poor Thiophene 1,1‐Dioxides: Synthesis, Characterization, and Application as Electron Relays in Photocatalytic Hydrogen Generation

Tsai

Chirdon

Kagalwala

et al. 2015

Chemistry A European J

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ChemInform Abstract: Electrochemical Behavior of Organic Molecules Containing Sulfur

Simonet

1994

ChemInform

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Cathodic cleavage of 1-trifluoromethyl alkenyl sulfone and sulfoxide

Jabbar

Bito

Kunugi

et al. 1998

Electrochimica Acta

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Electrochemical behavior of organic molecules containing sulfur

Cited by 10 publications

References 103 publications

Electron‐Poor Thiophene 1,1‐Dioxides: Synthesis, Characterization, and Application as Electron Relays in Photocatalytic Hydrogen Generation

Electron‐Poor Thiophene 1,1‐Dioxides: Synthesis, Characterization, and Application as Electron Relays in Photocatalytic Hydrogen Generation

ChemInform Abstract: Electrochemical Behavior of Organic Molecules Containing Sulfur

Cathodic cleavage of 1-trifluoromethyl alkenyl sulfone and sulfoxide

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