Electrochemical and Spectroscopic Study of Eu(III)/Eu(II) Couple in the 1-Ethyl-3-Methylimidazolium Bis(Trifluromethanesulfonyl)Imide Ionic Liquid

Bengio, David; Dumas, Thomas; Mendès, E.; Solari, Pier-Lorenzo; Husar, Richard; Schlegel, Michel L.; Pellet‐Rostaing, Stéphane

doi:10.1007/978-3-319-72350-1_9

Rare Metal Technology 2018

2018

DOI: 10.1007/978-3-319-72350-1_9

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Electrochemical and Spectroscopic Study of Eu(III)/Eu(II) Couple in the 1-Ethyl-3-Methylimidazolium Bis(Trifluromethanesulfonyl)Imide Ionic Liquid

David Bengio

Thomas Dumas

E. Mendès

et al.

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2022

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X-ray absorption spectroscopy and actinide electrochemistry: a setup dedicated to radioactive samples applied to neptunium chemistry

Husar¹,

Dumas²,

Schlegel³

et al. 2022

J Synchrotron Radiat

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A spectroelectrochemical setup has been developed to investigate radioactive elements in small volumes (0.7 to 2 ml) under oxidation–reduction (redox) controlled conditions by X-ray absorption spectroscopy (XAS). The cell design is presented together with in situ XAS measurements performed during neptunium redox reactions. Cycling experiments on the NpO2 2+/NpO2 + redox couple were applied to qualify the cell electrodynamics using XANES measurements and its ability to probe modifications in the neptunyl hydration shell in a 1 mol l−1 HNO3 solution. The XAS results are in agreement with previous structural studies and the NpO2 2+/NpO2 + standard potential, determined using Nernst methods, is consistent with measurements based on other techniques. Subsequently, the NpO2 +, NpO2 2+ and Np4+ ion structures in solution were stabilized and measured using EXAFS. The resulting fit parameters are again compared with other results from the literature and with theoretical models in order to evaluate how this spectroelectrochemistry experiment succeeds or fails to stabilize the oxidation states of actinides. The experiment succeeded in: (i) implementing a robust and safe XAS device to investigate unstable radioactive species, (ii) evaluate in a reproducible manner the NpO2 2+/NpO2 + standard potential under dilute conditions and (iii) clarify mechanistic aspects of the actinyl hydration sphere in solution. In contrast, a detailed comparison of EXAFS fit parameters shows that this method is less appropriate than the majority of the previously reported chemical methods for the stabilization of the Np4+ ion.

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X-ray absorption spectroscopy and actinide electrochemistry: a setup dedicated to radioactive samples applied to neptunium chemistry

Husar¹,

Dumas²,

Schlegel³

et al. 2022

J Synchrotron Radiat

Self Cite

View full text Add to dashboard Cite

show abstract

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Electrochemical and Spectroscopic Study of Eu(III)/Eu(II) Couple in the 1-Ethyl-3-Methylimidazolium Bis(Trifluromethanesulfonyl)Imide Ionic Liquid

Cited by 1 publication

References 23 publications

X-ray absorption spectroscopy and actinide electrochemistry: a setup dedicated to radioactive samples applied to neptunium chemistry

X-ray absorption spectroscopy and actinide electrochemistry: a setup dedicated to radioactive samples applied to neptunium chemistry

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