Electrochemical activation of CO₂by MOF-(Fe, Ni, Mn) derivatives of 5-aminoisophthalic acid and the thiazole group influence on its catalytic activity

Abstract

Five new coordination polymers, [Fe(AIP)] (1), [M(L)] [M = Fe (2), Ni (3)], [NiFe(L)] (4), and [Mn(L)] (5) (H2AIP = 5-aminoisophthalic acid, LH2 = 5-((thiazol-2-ylmethyl)amino)isophthalic acid), were synthesized under solvothermal...

Hydrosilylation and electroreduction of CO2using a zirconocene hydride catalyst

“…To identify the CO 2 reduction products, chronoamperometry was carried out with a fixed potential of E = À2.8 V; the released gases were bubbled in a solution containing a known amount of Wilkinson's catalyst, to trap any CO, allowing spectroscopic characterization, 22 and the characteristic carbonyl band was observed by FTIR (Fig. S13, ESI †).…”