Abstract:Soft adhesive pads are needed for many robotics applications, and one approach is based on electroadhesion. Here we present a general analytic model and numerical results for electroadhesion for soft solids with arbitrary time-dependent applied voltage, and arbitrary dielectric response of the solids, and including surface roughness. We consider the simplest coplanar-plate-capacitor model with a periodic array of conducting strips located close to the surface of the adhesive pad, and discuss the optimum geomet… Show more
“…roughness) on relevant size scale. [36][37][38] The applied load (P) and displacement (δ) are measured (Figure 2B) as the two perpendicularly crossed cylinders (with radius r = 10 mm, Figure S4) are brought together to generate contact between ES and AT layers at a constant speed of 0.05 mm/s, held at fixed displacement for 30 s to charge the ionoelastomers, and then separated with the same speed of 0.05 mm/s at fixed voltage (Figure S5). To measure the electrostatic force under steadystate conditions, we apply 30 s of charging time (Figure S6), which is longer than the RC time-scale for charging of the IDL (τ RC ≈ 60 ms) as well as the time-scale for stress-relaxation of the contact force (see Supporting Information for details).…”
Electro-adhesion provides a simple route to rapidly and reversibly control adhesion using applied electric potentials, offering promise for a variety of applications including haptics and robotics. Current electro-adhesives, however, suffer from key limitations associated with the use of high operating
“…roughness) on relevant size scale. [36][37][38] The applied load (P) and displacement (δ) are measured (Figure 2B) as the two perpendicularly crossed cylinders (with radius r = 10 mm, Figure S4) are brought together to generate contact between ES and AT layers at a constant speed of 0.05 mm/s, held at fixed displacement for 30 s to charge the ionoelastomers, and then separated with the same speed of 0.05 mm/s at fixed voltage (Figure S5). To measure the electrostatic force under steadystate conditions, we apply 30 s of charging time (Figure S6), which is longer than the RC time-scale for charging of the IDL (τ RC ≈ 60 ms) as well as the time-scale for stress-relaxation of the contact force (see Supporting Information for details).…”
Electro-adhesion provides a simple route to rapidly and reversibly control adhesion using applied electric potentials, offering promise for a variety of applications including haptics and robotics. Current electro-adhesives, however, suffer from key limitations associated with the use of high operating
“…window sealants), and medicine (e.g. tissue adhesives) are but a few industries that could benefit from electrocuring designs [5][6][7][8][9] . In addition, applications of Voltaglue could also be explored in the fields where PAMAM has been exploited such as-stimuli-responsive biomaterials, electrochemical sensors, conductive polymers, and controlled chemical releaseall applications that can benefit from voltage-activated adhesion [10][11][12][13][14][15][16][17] .…”
Voltage-activated adhesion is a relatively new discovery that relies on direct currents for initiation of crosslinking. Previous investigations have found that direct currents are linearly correlated to the migration rates of electrocuring, but this is limited by high voltages exceeding 100 V with instances of incomplete curing of voltage-activated adhesives on semiconducting substrates. Practical applications of electrocuring would benefit from lower voltages to mitigate high voltage risks, especially with regard to potential medical applications. Alternative electrocuring strategies based on alternating current (AC), electrolyte ionic radius, and temperature are evaluated herein. Square waveform AC electric fields are hypothesized to initiate a two-sided curing progression of voltage-activated adhesive (PAMAM-g-diazirine aka Voltaglue), where initiation occurs at the cathode terminal. Structure-activity relationships of AC frequency at currents of 1-3 mA are evaluated against direct currents, migration rate, storage modulus, and lap shear adhesion on ex-vivo tissue mimics. Numerous improvements in electrocuring are observed with AC stimulation versus DC, including a 35 % decrease in maximum voltage, 180 % improvement in kinetic rates, and 100 % increase in lap shear adhesion at 2 mA. Li + ion electrolytes and curing at 4 o C shift curing kinetics by +104 % and -22 % with respect to the control ion (Na + ion at 24 o C), suggesting electrolyte migration is the rate limiting step. Li + ion electrolytes and curing at 50 o C improves storage modulus by 110% and 470 % respectively. Further evaluations of electrocured matrices with 19 F NMR, solid-state NMR and infrared spectroscopy provide insights into the probable crosslinking mechanisms.
“…In fact, increasing roughness has been used to intentionally minimize vdW adhesion [16,25,[27][28][29]. The role of surface roughness on electrostatic forces has been studied in the context of electroadhesion [30][31][32][33][34], where potentials are applied to the conducting surface creating an attractive electrostatic force, but we are not aware of studies examining the role of sur face roughness in particle adhesion to grounded conducting surfaces.…”
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