Carbonization of epoxy resin under high voltage discharge
or exposure
to high temperatures results in insulation failure. Herein, multiscale
spherical boron nitride (SBN) epoxy resin is developed with improved
anticarbonization properties. The thermal conductivity, thermostability,
dielectric performances, volume resistivity, breakdown strength, and
flame retardancy of the epoxy-SBN composites were studied. The thermal
conductivity, thermostability, volume resistivity, and breakdown strength
of epoxy-SBN composites are higher than that of pure resin, with a
ratio of high thermal conductivity of 24 and a volume resistivity
of ∼10. The AC breakdown voltage of the epoxy-30SBN composites
was as high as 29.96 kV/mm. In addition, epoxy-30SBN composites possess
minimal carbonization surface area under high-voltage discharge. Increased
thermal conductivity, lower mass loss rate, high flame resistance,
and inhibited charge carrier migration contribute to the improved
carbonization resistance of the arc. Densified SBN networks in epoxy
resin act as a dense barrier to achieve anticarbonization under high
voltage stress or high-temperature exposure. Therefore, epoxy-SBN
composites are promising candidates for application in next-generation
high-voltage devices to ensure electrical safety.