Transparent p-type polycrystalline CuI films with high hole mobility are produced by solid iodination of Cu 3 N precursor layers and subsequent heat treatment at 120 C. The hole mobility reached 20 cm 2 V À1 s À1 in the CuI films fabricated on both glass and polyethylene terephthalate substrates. Furthermore, transparent p-n diodes with sufficiently high rectification ratio (6 Â 10 6 ) and ideality factor (1.6) are successfully fabricated by employing a heterojunction of p-type CuI and n-type amorphous In-Ga-Zn-O (a-IGZO) layers. The CuI/a-IGZO heterojunction exhibits the photovoltaic effect, with a short-circuit current of 0.33 mA and an open-circuit voltage of 10 mV under UV illumination at a wavelength of 365 nm and intensity of 1.9 mW cm À2 . The photoresponse at zero bias is sufficiently quick, and thus, the photovoltaic properties of the CuI/a-IGZO diodes rendere them potential candidates for visible-light-blind and self-powered UV photodetectors. These findings suggest that CuI is an excellent transparent p-type semiconductor that can be fabricated at low temperature.