“…The PL peaks could shift towards lower energy at a step proportional to the mean tail depth, and an overestimation of the ionization energy could result. The activation energy of the Mn acceptor in GaSb was estimated at 1672 meV from temperature-dependent Hall measurements [14,20]. The value corresponds very well with our estimation.…”
Section: Resultssupporting
confidence: 51%
“…Alternatively, one can use a simple physical concept presented in Ref. [20] to calculate a H and N I . For an acceptor ionization energy of 15.6 meV, one obtains a H around 24 Å , and consequently N I could be as high as 1.26 Â 10 18 cm À3 .…”
“…The PL peaks could shift towards lower energy at a step proportional to the mean tail depth, and an overestimation of the ionization energy could result. The activation energy of the Mn acceptor in GaSb was estimated at 1672 meV from temperature-dependent Hall measurements [14,20]. The value corresponds very well with our estimation.…”
Section: Resultssupporting
confidence: 51%
“…Alternatively, one can use a simple physical concept presented in Ref. [20] to calculate a H and N I . For an acceptor ionization energy of 15.6 meV, one obtains a H around 24 Å , and consequently N I could be as high as 1.26 Â 10 18 cm À3 .…”
“…These new states correspond to acceptors, as discussed above. They are derived from the valence band by the [11,14,15,16,17,18,19,20]) in respect to valence-band edges, whose relative positions are taken from Ref. [21].…”
mentioning
confidence: 99%
“…2: Experimental energies of Mn levels in the gap of III-V compounds according to Refs. [11,14,15,16,17,18,19,20]) in respect to valence-band edges, whose relative positions are taken from Ref. [21].…”
It is suggested that p-d hybridization contributes significantly to the hole binding energy E b of Mn acceptors in III-V compounds, leading in an extreme case to the formation of Zhang-Rice-like small magnetic polarons. The model explains both strong increase of E b and evolution of Mn spinresonance spectrum with the magnitude of valence-band offsets. For such a structure of Mn impurity in III-V materials, possible models accounting for the recently determined Curie temperature of about 940 K in a compensated Ga0.91Mn0.09N are discussed.
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