Electrical Properties and Valence Band Structure of GeSexTe1-x Single Crystals.-The anomalous dependence of the thermopower, Hall constant and of the electrical conductivity on the composition of Ge1y(Se0.2Te0.8)y (y = 0.495-0.510) single crystals is analyzed at room temp. on the basis of a two-carrier model. Both experimental and calculated results confirm the existence of a two-carrier valence-band structure due to the rhombohedral lattice distortion in α-GeSexTe1-x which causes a splitting of the valence-energy band at L extrema points at low temperature. -(GE, Y. R.; WIEDEMEIER, H.