Noninvasive electrophysiological signal monitoring is
significant
for health care and scientific research. The simultaneous achievement
of wet adhesion, stretchability, breathability, and low contact impedance
is highly recommended in the epidermal electrode but still challenging.
In this work, a monolayer porous film electrode with a pore size and
wall thickness of less than ∼10 μm is fabricated via
the breath figure method (BFM) and metal sputtering, and it was subsequently
applied using epidermal electrophysiological monitoring. The ultrahigh
permeability is comparable to the naked skin because the through holes
of the monolayer porous film match well with the pores on human skin.
The stretchability of 50% is realized with the combination of Au microcrack
and the monolayer porous structure. The wet adhesion of 0.17 N/cm
is established on the chemical bonding between the electrode and the
epidermis. The contact impedance is comparable with the gold standard
Ag/AgCl gel electrode, especially after sweating. Stable and precise
electrophysiological signals are measured. Especially, the perspiration
resistance of the monolayer porous film outperforms that of the gel
electrode. The monolayer porous structure provides a new avenue to
improve the breathability of the epidermal electronics.