Enabling unique architectures and functionalities of microsystems for numerous applications in electronics, photonics and other areas often requires microassembly of separately prepared heterogeneous materials instead of monolithic microfabrication. However, microassembly of dissimilar materials while ensuring high structural integrity has been challenging in the context of deterministic transferring and joining of materials at the microscale where surface adhesion is far more dominant than body weight. Here we present an approach to assembling microsystems with microscale building blocks of four disparate classes of device-grade materials including semiconductors, metals, dielectrics, and polymers. This approach uniquely utilizes reversible adhesion-based transfer printing for material transferring and thermal processing for material joining at the microscale. The interfacial joining characteristics between materials assembled by this approach are systematically investigated upon different joining mechanisms using blister tests. The device level capabilities of this approach are further demonstrated through assembling and testing of a microtoroid resonator and a radio frequency (RF) microelectromechanical systems (MEMS) switch that involve optical and electrical functionalities with mechanical motion. This work opens up a unique route towards 3D heterogeneous material integration to fabricate microsystems.While monolithic microfabrication has been quite successful in the manufacturing of microsystems such as integrated circuits (IC) and microelectromechanical systems (MEMS) 1,2 , continued innovation towards three dimensional (3D) architectures and heterogeneous integration has been limited, which would otherwise enable improvements in performance and novel functionalities of microsystems. Associated challenges originate from layer-by-layer thin film processing on a single substrate and dissimilar nature of materials that may need different techniques to process. Consequently, 3D heterogeneous integration often requires independent fabrication of constituents followed by microassembly rather than monolithic microfabrication. In this context, transfer printing 3,4 has emerged as a method that utilizes highly reversible surface adhesion of a polymeric stamp to deterministically transfer microscale solid objects called "inks". The ability to transfer inks from a donor substrate where inks are grown and processed to a receiving substrate where inks are finally assembled reduces the complexity of manufacturing processes regarding heterogeneous material integration. Furthermore, previously reported micro-masonry 5 which relies on transfer printing demonstrates that after proper thermal processing, direct bonding between transferred silicon inks can be achieved, which may be sufficiently strong to produce various MEMS devices 6-8 . However, limited assembling material classes and quantitatively unknown interfacial characteristics between joined inks suppress broader adaptation of this transfer printing-based microasse...