Electrical Conductivity Studies of Polyaniline Nanotubes Doped with Different Sulfonic Acids

Khalid, Mohd; Tumelero, Milton A.; Brandt, Iuri S.; Zoldan, Vinícius C.; Acuña, J.J.S.; Pasa, André A.

doi:10.1155/2013/718304

Cited by 36 publications

(29 citation statements)

References 43 publications

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“…Once a good image was achieved, the scan was set to 10 µm × 10 µm at 0.1 Hz and 512 lines. 45 To study the effect of PANI protonation level on the surface topography, AFM was utilized to determine the rms surface roughness. Roughness analysis and surface area were performed for each scan.…”

Section: Methodsmentioning

confidence: 99%

Tuning the work function of polyaniline via camphorsulfonic acid: an X-ray photoelectron spectroscopy investigation

et al. 2015

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In the present work, we present the first demonstration to tune the work function of polyaniline by controlling the concentration level of camphorsulfonic acid as a protonic acid dopant and m-cresol as a solvent. Optical, thermal, structural, and electronic properties, along with surface topography and elemental analysis of protonated polyaniline, were studied in detail to investigate the effect of camphorsulfonic acid on the work function of polyaniline. Results showed that an increase in camphorsulfonic acid content induces a gradual transformation in polyaniline structure from an emeraldine base to an emeraldine salt phase, which is associated with an increase in electrical conductivity and an improvement in crystallinity. X-ray photoelectron spectroscopy was used to evaluate the work function and to determine the elemental composition of the surface and several atomic layers beneath the surface. Results showed that raising camphorsulfonic acid content from quarter protonated to fully protonated leads to an increase in the work function of polyaniline from 4.42 ±0.14 eV to 4.78 ±0.13 eV, respectively.

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Section: Methodsmentioning

confidence: 99%

Tuning the work function of polyaniline via camphorsulfonic acid: an X-ray photoelectron spectroscopy investigation

et al. 2015

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“…The most popular method for particle-size determination is the use of dynamic light scattering [51]. The morphology of conducting polymer film is usually determined with the use of microscopic methods, mainly AFM, SEM and TEM [52][53][54]. Having the fundamental properties and parameters of particular materials used for developed composite, the parametrization of a percolation problem is possible.…”

Section: Modeling Of Percolation Systemsmentioning

confidence: 99%

Concept of a Conducting Composite Material for Lightning Strike Protection

Katunin

Krukiewicz

Herega

et al. 2016

Advances in Materials Science

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The paper focuses on development of a multifunctional material which allows conducting of electrical current and simultaneously holds mechanical properties of a polymeric composite. Such material could be applied for exterior fuselage elements of an aircraft in order to minimize damage occurring during lightning strikes. The concept introduced in this paper is presented from the points of view of various scientific disciplines including materials science, chemistry, structural physics and mechanical engineering with a discussion on results achieved to-date and further plans of research.

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“…The morphology and other properties of nanostructured SPAn are dependent, apart from the nature of dopant [13,14], on the amount of dopant and An concentration, since it is difficult to produce polymers only from sulfonic acid derivatives of An because of the low reactivity of the monomer due to the presence of electron-attracting sulfonic groups [15,16].…”

Section: Introductionmentioning

confidence: 99%

Electrodeposition of self-doped copolymers of aniline with aminobenzensulfonic acids on stainless steel. Morphological and electrochemical characterization

Michael

Prochaska

Sazou

2015

J Solid State Electrochem

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Self-doped conducting polyaniline (PAn) films were deposited on passive stainless steel (SS) AISI304 substrates by cyclic potential sweep deposition from aqueous mixed monomer solutions of aniline (An) and different aminobenzenesulfonic acids (2-, 3-or, 4-aminobenzenesulfonic acid, ABSA), without the presence of a supporting electrolyte. Two different An concentrations were examined (0.01 and 0.05 M), while the concentration of each ABSA used was kept constant at 0.

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Electrical Conductivity Studies of Polyaniline Nanotubes Doped with Different Sulfonic Acids

Cited by 36 publications

References 43 publications

Tuning the work function of polyaniline via camphorsulfonic acid: an X-ray photoelectron spectroscopy investigation

Tuning the work function of polyaniline via camphorsulfonic acid: an X-ray photoelectron spectroscopy investigation

Concept of a Conducting Composite Material for Lightning Strike Protection

Electrodeposition of self-doped copolymers of aniline with aminobenzensulfonic acids on stainless steel. Morphological and electrochemical characterization

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