“…The broad and diffuse T O‐T peaks suggest that the samples undergo phase transition between O and T phases in a wide temperature range (e.g., from room temperature to 200°C), which is consistent with the refined XRD result that O and T phases may coexist at room temperature. Furthermore, due to the presence of diffuse phase transition at T c in the ceramics, the modified Curie–Weiss law is used to describe diffuseness of phase transition:
where C is a constant, ε r is dielectric constant, T m is the temperature at which ε r reaches a maximum, and ε m is the maximum value of ε r at T m
33,34 . Moreover, the dispersion factor (γ) is in the range between 1 (a normal ferroelectric) and 2 (an ideal relaxor ferroelectric), which can be obtained by fitting the function between ln( ε r − ε m ) and ln( T − T m ).…”