The development of dielectric barrier discharge (DBD) in glow mode in large gaps in air at atmospheric pressure, due to providing diffuse, uniform, safe, and economic treatments for a wide range of substrates and for many applications, could be a beneficial way to enhance cold plasma applications in various industries. Here, we generated a glow DBD that has a volume-surface coupling geometrical structure in a 1mm gap distance by a pulsed power supply and expanded the gap distance up to 2 cm by modulating the pulsed power supply on an AC one. The resulting glow discharges were studied by voltage-current waveform and atomic emission spectroscopy.