1994
DOI: 10.1515/znb-1994-0210
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Ein neues Inselpolyborat: Das Heptaboration in einem Silberikosadiborat / A New Polyborate: The Heptaborate Ion in a Silver Icosadiborate

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Cited by 4 publications
(1 citation statement)
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“…The substitution of the diamine protons by alkyl chains in the silver complex obviously has a blocking effect on the polymerization. A related dinuclear silver complex, [Ag 2 H 2 (en) 3 ] 4+ , has previously been identified by X‐ray crystallographic analysis 14b. In that case, the ethylenediamine bridges are cleaved by protonation to form a dinuclear complex where only one ethylenediamine ligand bridges two silver ions; the coordination number of the silver ion is two.…”
Section: Resultsmentioning
confidence: 99%
“…The substitution of the diamine protons by alkyl chains in the silver complex obviously has a blocking effect on the polymerization. A related dinuclear silver complex, [Ag 2 H 2 (en) 3 ] 4+ , has previously been identified by X‐ray crystallographic analysis 14b. In that case, the ethylenediamine bridges are cleaved by protonation to form a dinuclear complex where only one ethylenediamine ligand bridges two silver ions; the coordination number of the silver ion is two.…”
Section: Resultsmentioning
confidence: 99%