This paper describes some poled electrooptic bulk polymers (EOP) of the guest/host type having a cured epoxy resin as the host. The electrooptic polymers oftypical dimensions 13x13x3 mm are characterized with respect to application as Pockels materials in an optical high voltage sensor. The electrooptic coefficients obtained here are of the same order of magnitude as those which are required for high voltage applications. An optical sensor based on disperse red 1 dye and an epoxy polymer is developed. It is able to measure voltages up to 10 kV AC. It is shown that bulk EOP can be produced with relatively large physical dimensions comparable to commercially available Pockels crystals. A technique is described which compensates for the inevitable intrinsic birefringence built into most bulk polymers. The epoxy based EOP shows high orientational stability, even when compared with a polysulfone based EOP having a higher glass transition temperature.Keywords: Electrooptic polymer, nonlinear optical dye, epoxy, fiber optic sensor, high voltage, Disperse Red 1.
INTRODUCTIONOver the last decade, electrooptic polymers have been the object of extensive research,1'2'3. Most effort has been focused on obtaining very high electrooptic coefficients, modest optical absorptions and acceptable long-term stability of the electrooptic polymer. The electrooptic polymers have not yet found any widespread commercial use, because present materials do not meet the demands set by waveguide modulator applications. Materials having acceptable longterm stability, do in general have too low a magnitude of the electrooptic coefficient. This paper presents a high voltage sensor using an electrooptic polymer, where the demands with regard to electrooptic coefficient and maximum operational temperature are less critical as compared to waveguide applications in microelectronics. The electric power utilities are persistently working on reducing costs, thus running a very complex electric power system in a minimum cost state. For this purpose, the power utilities want to be able to measure the voltage and current at a large number of sites. Optical sensors would be well suited for electric power systems because they provide alvanic insulation to the high voltage potential, and they are insensitive to electro magnetic induced noise4S0. Section three in this paper describes the optical measurement principle of the prepared experimental high voltage sensor. Section four to six describe the preparation process and material properties of the EOP materials. The concept of making an optical high voltage sensor based on the EOP material was shown in l990. The EOP serves two purposes in the optical sensor. 1) It provides the electrical insulation between a high voltage electrode and ground potential, 2) The voltage is measured optically using the electrooptic effect of the polymer, with the full high voltage applied over the polymer material. For comparison, electrooptic crystals do not easily insulate for more than a few kV, thus a special voltag...