Let S be a reduced E-Fountain semigroup. If S satisfies the congruence condition, there is a natural construction of a category C associated with S. Under a few conditions, we prove that there is an isomorphism of algebras kS ≃ kC (where k is any unital commutative ring) if some weak form of the right ample identity holds in S. This gives a unified generalization for a result of the author on right restriction E-Ehresmann semigroups and a result of Margolis and Steinberg on the Catalan monoid.