Efficient Removal of Heavy Metals from Contaminated Sunflower Straw by an Acid-Assisted Hydrothermal Process

Abstract

The removal of heavy metals is crucial to the utilization of contaminated biomass resources. In this study, we report an efficient process of hydrothermal conversion (HTC) of sunflower straw (Helianthus annuus L.) to remove heavy metals. The effect of different HTC temperatures and concentrations of HCl additives on heavy metal removal efficiency was investigated. The results revealed that increasing the temperature or concentration of HCl promoted the transfer of heavy metals from hydrochar to liquid products during HTC. The heavy metals removed to the liquid products included up to 99% of Zn and Cd, 94% of Cu, and 87% of Pb after hydrothermal conversion with a temperature of 200 °C and HCl 2%. The species of heavy metals in hydrochars converted from unstable to stable with an increase in temperature from 160 °C to 280 °C. The stable fractions of heavy metals in the acidic condition decreased as the acid concentration increased. This aligns well with the high transfer efficiency of heavy metals from the solid phase to the liquid phase under acidic conditions. The FTIR indicated that the carboxy and hydroxy groups decreased significantly as the temperature increased and the concentration of HCl increased, which promoted the degradation of sunflower straw. A scan electron microscope showed that the deepening of the destruction of the initial microstructure promotes the transfer of heavy metals from hydrochars to liquid phase products. This acid-assisted hydrothermal process is an efficient method to treat biomass containing heavy metals.

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“…Nonetheless , Fei et al (2019) and Song et al (2023) demonstrated the reduction of heavy metal retention in hydrochar by removing the elements from the hydrochar to the liquid products. In a study conducted by Song et al (2023), it was observed that the hydrothermal carbonization of sunflower straws at 200 °C, coupled with a 2% hydrochloric acid pre-treatment, resulted in significant removal of zinc, cadmium, copper, and lead. The maximum removal percentages for these heavy metals from the hydrochar to the liquid product were reported as 99, 99, 94, and 87%, respectively.…”