Solid state dye doped polymer is an attractive alternative to the conventional liquid dye solution. In this paper, the laser characteristics of LD490 (LD490) doped polymethy J methacrylate (PMMA) rods modified with dioxane are studied under third harmonic Nd : YAG laser excitation ill a transverse l'umP configuration and the variation of gain coefficient of the dye in solid mediumfor different pump powers is studied.The photobleaching of dye molecule in polymer medium under third harmonic Nd : YAG laser excilion is also studied for various pump enel'gy.