Abstract:This paper reports on ZnO nano-whiskers (ZNWs), synthesized by sol-gel method at a pre-determined speed by using zinc acetate dehydrate and a cationic surfactant, N-cetyl-N,N,N-trimethyl ammonium bromide (CTAB) . The effect of pre-determined stirring condition on the particle size, aspect-ratio and morphology of ZNWs has been studied. The SEM and TEM result shows that zinc oxide developed into the huge colony consisting of adequate ZnO nano-whiskers, which contained a large number of long needle-like whiskers … Show more
“…The size characterization of ZnO-NPs was performed using a Transmission electron microscope (TEM) (JEM-2100F; Jeol, Tokyo, Japan) 23 featuring ultra high resolution and rapid data acquisition. The lyophilized ZnO-NPs was suspended in 20 mM phosphate-buffered saline (PBS, pH 7.4) and a drop of the nanoparticles was mounted on a clear glass stub, air-dried, and coated with gold-palladium alloy using a sputter coater.…”
The effect of mechanical stirring on sol-gel synthesis of thorn-like ZnO nanoparticles (ZnO-NPs) and antimicrobial activities is successfully reported in this study. The in-house synthesized nanoparticles were characterized by XRD, SEM, TEM, FTIR, TGA, DSC and UV-visible spectroscopy. The X-Ray Diffraction analysis revealed the wurtzite crystal lattice for ZnO-NPs with no impurities present. The diametric measurements of the synthesized thorn-like ZnO-NPs (morphology assessed by SEM) were well accounted to be less than 50 nm with the help of TEM. Relative decrease in aspect ratio was observed on increasing the agitation speed. The UV-visible spectroscopy showed the absorption peaks of the ZnO-NPs existed in both UVA and UVB region. A hypsochromic shift in λmax was observed when stirring pace was increased from 500 rpm to 2000 rpm. The FTIR spectroscopy showed the absorption bands of the stretching modes of Zn-O between 500 cm−1 to 525 cm−1. The Thermal analysis studies revealed better stability for ZnO-NPs prepared at 2000 rpm (ZnO-2000 rpm). TGA revealed the weight loss between two main temperatures ranges viz. around (90 °C–120 °C) and (240 °C–280 °C). Finally, the effect of ZnO-NPs prepared at different stirring conditions on the growth of Gram-positive (Bacillus subtilis), Gram-negative (Escherichia coli) bacteria and a fungi (Candida albicans) were examined; which showed good antibacterial as well as antifungal properties. These findings introduce a simple, inexpensive process to synthesize ZnO-NPs using conventional methods without the use of sophisticated equipments and its application as a potent nano-antibiotic.
“…The size characterization of ZnO-NPs was performed using a Transmission electron microscope (TEM) (JEM-2100F; Jeol, Tokyo, Japan) 23 featuring ultra high resolution and rapid data acquisition. The lyophilized ZnO-NPs was suspended in 20 mM phosphate-buffered saline (PBS, pH 7.4) and a drop of the nanoparticles was mounted on a clear glass stub, air-dried, and coated with gold-palladium alloy using a sputter coater.…”
The effect of mechanical stirring on sol-gel synthesis of thorn-like ZnO nanoparticles (ZnO-NPs) and antimicrobial activities is successfully reported in this study. The in-house synthesized nanoparticles were characterized by XRD, SEM, TEM, FTIR, TGA, DSC and UV-visible spectroscopy. The X-Ray Diffraction analysis revealed the wurtzite crystal lattice for ZnO-NPs with no impurities present. The diametric measurements of the synthesized thorn-like ZnO-NPs (morphology assessed by SEM) were well accounted to be less than 50 nm with the help of TEM. Relative decrease in aspect ratio was observed on increasing the agitation speed. The UV-visible spectroscopy showed the absorption peaks of the ZnO-NPs existed in both UVA and UVB region. A hypsochromic shift in λmax was observed when stirring pace was increased from 500 rpm to 2000 rpm. The FTIR spectroscopy showed the absorption bands of the stretching modes of Zn-O between 500 cm−1 to 525 cm−1. The Thermal analysis studies revealed better stability for ZnO-NPs prepared at 2000 rpm (ZnO-2000 rpm). TGA revealed the weight loss between two main temperatures ranges viz. around (90 °C–120 °C) and (240 °C–280 °C). Finally, the effect of ZnO-NPs prepared at different stirring conditions on the growth of Gram-positive (Bacillus subtilis), Gram-negative (Escherichia coli) bacteria and a fungi (Candida albicans) were examined; which showed good antibacterial as well as antifungal properties. These findings introduce a simple, inexpensive process to synthesize ZnO-NPs using conventional methods without the use of sophisticated equipments and its application as a potent nano-antibiotic.
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