Efficient H 2 production from formic acid by a supported iron catalyst on silica

Formic Acid or Formate Derivatives as the In Situ Hydrogen Source in Au‐Catalyzed Reduction of para‐Chloronitrobenzene

“…It had been reported that Au catalyst show superior activity on the decomposition of HCOOH. Furthermore, Au catalyst owning high selectivity hydrogenation of para‐ chloronitrobenzene, compared to other precious metal, have attracted much attention . Thus, it is of interest to examine the catalytic hydrogenation of para‐ chloronitrobenzene over Au catalyst with HCOOH or formate derivatives as the reducing agent precursor.…”

Solid Molecular Phosphine Catalysts for Formic Acid Decomposition in the Biorefinery

“…[11] They are typically studied in the context of hydrogen storage and fuel-cell applications. [16] Bavykina et al reported ab iphenyl/pyridinebased CTF (covalent triazine framework) loaded with [Cp*Ir-(OH)] for FA decomposition. Recent reviews highlight that supported metal catalysts typically exhibit lower activities and selectivities than homogeneous catalysts.…”

“…Stathi et al immobilized Fe II on phosphine-modified SiO 2 and obtained TOFs up to 7600 h À1 at 93 8 8C. [16] Bavykina et al reported ab iphenyl/pyridinebased CTF (covalent triazine framework) loaded with [Cp*Ir-(OH)] for FA decomposition. At 80 8 8C, TOFs up to 27 000 h À1 were obtained.…”

Molekulare Phosphan‐Feststoffkatalysatoren zur Ameisensäurezersetzung in der Bioraffinerie

“…Stathi et al immobilisierten Fe II auf phosphanmodifiziertem SiO 2 und erzielten bei 93 8 8CT OFs über 7600 h À1 . [16] Bavykina et al berichteten über mit [Cp*Ir-(OH)] beladene Biphenyl/Pyridin-basierte CTF-Materialien (CTF:c ovalent triazine framework) zur Ameisensäurezersetzung.D amit erreichten sie bei 80 8 8Ce ine TOFv on 27 000 h À1 . [17] Diese Untersuchungen belegen das große Potenzial immobilisierter Katalysatoren.…”