Efficient electrochemical synthesis of a manganese-based metal–organic framework for H₂ and CO₂ uptake

Abstract

Electrochemical synthesis, from manganese strips and dissolved linker, of a new amine-containing manganese-based metal–organic framework with enhanced CO2 uptake.

First-row transition metal-based materials derived from bimetallic metal–organic frameworks as highly efficient electrocatalysts for electrochemical water splitting

“…68,69 Electrochemical syntheses provide uniform and rapid growth of MOFs on conductive substrates by in situ generation of metal ions that react as they are formed with the organic linker present in the solution. 70 The use of different substrates and layer thickness control may…”

Recent advances on electrochemical methods in fabricating two‐dimensional organic‐ligand‐containing frameworks

“…Recently, the amine‐based manganese MOF, namely Mn‐DABDC(ES), was synthesized by Iqbal and Easun et al via electrochemical method under the optimal conditions of 70 mA current for 2 h at room temperature, and the yields were as high as 93% 69 . A distilled water/DMF (1:3 vol/vol) solution containing 75 mmol/L of 2,5‐diaminoterephthalic acid and 67.5 mmol/L of NaNO 3 was prepared.…”

“…Therefore, the anodic‐dissolution‐synthesized MOFs often feature good crystallinity as well as good properties. For instance, the electrosynthesized Mn‐DABDC(ES) exhibits higher CO 2 and H 2 adsorption than that of solvothermally synthesized Mn‐DABDC(ST) 69 . Moreover, the anodic ECD endows UiO‐66 good crystallinity as well as unique aggregation mode, thereby providing it with an excellent capability of sampling and concentration of volatile organics 68 .…”

Low-Pressure CO2 Capture in Zeolite Imidazole Frameworks with Ultramicropores Studied by Positron Annihilation

“…Furthermore, the methods used to synthesize MOF materials are flexible. In addition to the conventional solvothermal approach, MOFs can also be synthesized via an electrochemical method or an ultrasonication method. , Specifically, ZIFs are promising materials for CO 2 capture and separation from flue gas, which plays a significant role in alleviating global warming …”

“…In addition to the conventional solvothermal approach, MOFs can also be synthesized via an electrochemical method or an ultra- sonication method. 15,16 Specifically, ZIFs are promising materials for CO 2 capture and separation from flue gas, 17 which plays a significant role in alleviating global warming. 18 To date, many researchers have focused on the CO 2 adsorption properties of ZIFs by performing both experiments and calculations.…”